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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
phototransformation in water
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Scientifically acceptable publication

Data source

Referenceopen allclose all

Reference Type:
publication
Title:
Influence of humic substances on Photolysis of nitroaromatic compounds in aqueous systems
Author:
Simmons M.S. & Zepp R.G.
Year:
1986
Bibliographic source:
Water Research 20: 899-904
Reference Type:
secondary source
Title:
European Union Risk Assessment Report, Nitrobenzene, CAS No: 98-95-3
Author:
European Chemicals Bureau
Year:
2007
Bibliographic source:
3rd Priority List, Volume: 77

Materials and methods

Study type:
direct photolysis
Principles of method if other than guideline:
Direct photolysis in water was studied in distilled water and in the presence of humic substances respectively. A very diluted aqueous nitrobenzene solution was exposed to irradiation. The influence of humic substances on photoreactions was determined by comparing results in humus-containing water with those in distilled water.
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
Nitrobenzene
EC Number:
202-716-0
EC Name:
Nitrobenzene
Cas Number:
98-95-3
Molecular formula:
C6H5NO2
IUPAC Name:
nitrobenzene
Details on test material:
- Name of test material (as cited in study report): Nitrobenzene

Study design

Analytical method:
high-performance liquid chromatography
Light source:
other: irradiation
Light spectrum: wavelength in nm:
313
Details on light source:
Artificial light source
- Emission wavelength spectrum: 313
- Filters used and their purpose: Corning 0-52 snf 7-37 filters
Sensitiser (for indirect photolysis)
Type of sensitiser:
OH radical
Duration of test at given test condition
Initial conc. measured:
0 mol/L

Results and discussion

Spectrum of substance
Parameter:
max lambda
Value:
313 nm
Dissipation half-life of parent compound
DT50:
133 d

Any other information on results incl. tables

A direct photolysis constant of 5.2*E-03/d is given.

Applicant's summary and conclusion