EU-SAFETY_HEALTH_WORK-PREAMBLE

Safety and Health of Workers at Work Directive - Hazardous Substances

EU. Hazardous Substances for Purposes of Directive 89/391/EEC, 29 June 1989, amended by Regulation 1137/2008/EC, 21 November 2008 (Table 3/Annex VI, CLP; Annex III, 2000/54/EC)

This list contains a non-exhaustive inventory of substances that fall within the scope of the European Union's definition of hazardous chemical and biological substances, as provided on: (1) Table 3 of Annex VI to the CLP Regulation 1272/2008/EC; and (2) Annex III of Directive 2000/54/EC (Biological Agents). The EU's Occupational Safety and Health (OSH) Framework Directive 89/391/EEC applies to risks arising from chemical, physical and biological agents at the workplace.

Last updated 29 March 2024. Database contains 4662 unique substances/entries.
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604-105-8
139001-49-3
Carc. 2; Repr. 2; Skin Sens. 1
247-656-6
26399-36-0
Eye Irrit. 2
255-255-2
41198-08-7
Acute Tox. 4
425-740-5
-
Eye Dam. 1
BROWN JR 547
419-260-5
-
Eye Dam. 1
266-994-5
67747-09-5
Acute Tox. 4
-
-
B Bacteria and similar species
245-387-9
23031-36-9
Acute Tox. 3; Acute Tox. 4
-
-
V Viruses: Member States are to ensure that all viruses which have already been isolated in humains and which have not been assessed and allocated in this Annex are classified in group 2 as a minimum, except where Member States have proof that they are unlikely to cause disease in humans.
ORANGE DER 8068
422-980-2
187026-95-5
Eye Dam. 1
432-240-0
12056-51-8
Carc. 2
425-830-4
-
Eye Dam. 1
SUMIFIX BRILLIANTBLAU GL KONZENTRAT
414-100-0
154336-20-6
Eye Dam. 1
C.I. REACTIVE RED 231
402-150-6
-
Eye Irrit. 2; Skin Sens. 1
REAKTIVROT 2713
412-490-7
-
Skin Sens. 1
C.I. REACTIVE YELLOW 138:1
403-810-6
140876-13-7
Eye Dam. 1
-
5787-96-2
Acute Tox. 3; STOT RE 2
253-390-1
37199-66-9
Skin Corr. 1B
231-760-3
7722-64-7
Ox. Sol. 2; Repr. 2; Acute Tox. 4
220-527-1
2795-39-3
Carc. 2; Repr. 1B; STOT RE 1; Acute Tox. 4; Lact.
231-912-9
7778-74-7
Ox. Sol. 1; Acute Tox. 4
231-911-3
7778-73-6
Carc. 2; Acute Tox. 2; Acute Tox. 3; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2
231-832-4
7758-09-0
Ox. Sol. 2; Acute Tox. 3
POTASSIUM-P-TOLYLSULFIMIDE
406-650-5
97888-41-0
Eye Dam. 1
POTASSIUM N-(4-FLUOROPHENYL)GLYCINATE
415-710-1
184637-63-6
STOT RE 2; Eye Dam. 1; Skin Sens. 1
D(-) VALINE DANE SALT
427-240-2
134841-35-3
Skin Sens. 1
EURELYT
400-040-2
12091-08-6
Flam. Sol. 1; Water-react. 1; Skin Corr. 1A; Acute Tox. 4
212-736-1
865-33-8
Self-heat. 1; Skin Corr. 1B
FEKPDTA; KFEPDTA
405-680-6
148434-01-9
Self-heat. 2
215-181-3
1310-58-3
Acute Tox. 4; Skin Corr. 1A
231-594-1
7646-93-7
Skin Corr. 1B; STOT SE 3
232-151-5
7789-23-3
Acute Tox. 3
430-010-4
12160-44-0
Skin Corr. 1B; Skin Sens. 1
213-029-0
917-58-8
Self-heat. 1; Skin Corr. 1B
231-906-6
7778-50-9
Ox. Sol. 2; Carc. 1B; Muta. 1B; Repr. 1B; Acute Tox. 2; Acute Tox. 3; STOT RE 1; Acute Tox. 4; Skin Corr. 1B; Resp. Sens. 1; Skin Sens. 1
209-676-3
590-28-3
Acute Tox. 4
232-140-5
7789-00-6
Carc. 1B; Muta. 1B; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2; Skin Sens. 1
223-289-7
3811-04-9
Ox. Sol. 1; Acute Tox. 4
231-829-8
7758-01-2
Ox. Sol. 1; Carc. 1B; Acute Tox. 3
CHEMICAL CHELATING AGENT #2
411-640-9
153352-59-1
Acute Tox. 4
232-156-2
7789-29-9
Acute Tox. 3; Skin Corr. 1B
426-620-5
619297-89-1
Eye Dam. 1
V67282
406-500-9
174393-75-0
Skin Sens. 1
426-300-5
-
Eye Dam. 1
233-002-7
10007-85-9
Eye Irrit. 2
AZYLACID-POTASSIUMSALT
401-630-2
96566-70-0
Acute Tox. 4; Eye Irrit. 2; STOT SE 3
KLOBENPROP
426-350-8
138666-92-9
Acute Tox. 4; STOT RE 2; Eye Dam. 1; Skin Sens. 1
FLEXSORB HP SOLID; MALINE K
405-560-3
120447-91-8
Acute Tox. 4; Skin Corr. 1A
DUPLOSAN-DP-KALIUM
413-580-9
113963-87-4
Acute Tox. 4; Skin Irrit. 2; Eye Dam. 1; Skin Sens. 1
POTASSIUM 2,5-DICHLOROBENZOATE
415-700-5
184637-62-5
Acute Tox. 4; Eye Dam. 1
418-260-2
183196-57-8
Skin Sens. 1
418-260-2
183196-57-8
Repr. 1B; Skin Sens. 1
613-953-8
66603-10-9
Flam. Sol. 1; Acute Tox. 3; STOT RE 2; Skin Irrit. 2; Eye Dam. 1
246-376-1
24634-61-5
Eye Irrit. 2
231-119-8
7440-09-7
Water-react. 1; Skin Corr. 1B
-
299-45-6
Acute Tox. 2; Acute Tox. 1
-
-
B Bacteria and similar species
X4060
404-035-6
1379801-27-0
Skin Sens. 1
PAA HCL; PAA HCL 10L; PAA HCL 10S; PAA HCL 3L; PAA HCL 3S; PAA HCL H; PAA HCL L
415-050-2
71550-12-4
Acute Tox. 4; Skin Sens. 1
608-723-9
32289-58-0
Carc. 2; Acute Tox. 2; Acute Tox. 4; STOT RE 1; Eye Dam. 1; Skin Sens. 1B
608-042-7
27083-27-8
Carc. 2; Acute Tox. 2; Acute Tox. 4; STOT RE 1; Eye Dam. 1; Skin Sens. 1B
215-648-1
1336-36-3
STOT RE 2
427-280-0
176429-27-9
STOT SE 3; Skin Irrit. 2; Eye Dam. 1
427-480-8
176429-22-4
STOT SE 3; Skin Irrit. 2; Eye Dam. 1
RX-33
419-590-1
-
Flam. Sol. 1; Skin Sens. 1
BIOPOL HX
403-300-3
127536-43-0
Skin Sens. 1
AOC 2050X
403-430-0
138360-92-6
Eye Dam. 1
-
-
V Viruses: Member States are to ensure that all viruses which have already been isolated in humains and which have not been assessed and allocated in this Annex are classified in group 2 as a minimum, except where Member States have proof that they are unlikely to cause disease in humans.
-
-
B Bacteria and similar species
432-400-1
10102-09-7
Skin Corr. 1A
-
-
P Parasites
-
-
P Parasites
263-072-4
61789-60-4
Carc. 1B
The residue from the distillation of a mixture of coal tar and aromatic petroleum streams. A solid with a softening point from 40°C to 180°C (104°F to 356°F). Composed primarily of a complex combination of three or more membered condensed ring aromatic hydrocarbons.
269-109-0
68187-57-5
Carc. 1B
A complex black solid or semi-solid obtained from the distillation of a low temperature coal tar. It has a softening point within the approximate range of 40°C to 180°C (104°F to 356°F). Composed primarily of a complex mixture of hydrocarbons.
292-651-4
90669-57-1
Carc. 1B
The product obtained by air-blowing, at elevated temperature, low-temperature coal tar pitch. It has a softening-point within the approximate range of 70°C to 180°C (158°F to 356°F). Composed primarily of a complex mixture of hydrocarbons.
292-654-0
90669-59-3
Carc. 1B
A complex black solid obtained by the heat treatment of low temperature coal tar pitch. It has a softening point within the approximate range of 50°C to 140°C (122°F to 284°F). Composed primarily of a complex mixture of aromatic compounds.
292-653-5
90669-58-2
Carc. 1B
The residue from the distillation of high temperature coal tar. A black solid with an approximate softening point from 30°C to 180°C (86°F to 356°F). Composed primarily of a complex mixture of three or more membered condensed ring aromatic hydrocarbons.
266-028-2
65996-93-2
Carc. 1A; Muta. 1B; Repr. 1B
The residue obtained during the distillation of high boiling fractions from bituminous coal high temperature tar and/or pitch coke oil, with a softening point of 140° to 170°C (284°F to 392°F) according to DIN 52025. Composed primarily of tri- and polynuclear aromatic compounds which also contain heteroatoms.
302-650-3
94114-13-3
Carc. 1B
The heat treated residue from the distillation of high temperature coal tar. A black solid with an approximate softening point from 80°C to 180°C (176°F to 356°F). Composed primarily of a complex mixture of three or more membered condensed ring aromatic hydrocarbons.
310-162-7
121575-60-8
Carc. 1B
249-528-5
29232-93-7
Acute Tox. 4; STOT RE 1
245-704-0
23505-41-1
Acute Tox. 3; Acute Tox. 4
245-430-1
23103-98-2
Carc. 2; Acute Tox. 3; Skin Sens. 1
607-329-4
24151-93-7
Acute Tox. 4
200-076-7
51-03-6
STOT SE 3; Eye Irrit. 2
203-813-0
110-89-4
Flam. Liq. 2; Acute Tox. 3; Skin Corr. 1B
217-775-8
1951-97-9
Repr. 2; Eye Irrit. 2; Skin Irrit. 2; Resp. Sens. 1; Skin Sens. 1
228-042-7
6094-40-2
Repr. 2; Eye Irrit. 2; Skin Irrit. 2; Resp. Sens. 1; Skin Sens. 1
205-551-2
142-64-3
Repr. 2; Eye Irrit. 2; Skin Irrit. 2; Resp. Sens. 1; Skin Sens. 1
203-808-3
110-85-0
Repr. 2; Skin Corr. 1B; Resp. Sens. 1; Skin Sens. 1
203-808-3
110-85-0
Repr. 2; Skin Corr. 1B; Resp. Sens. 1; Skin Sens. 1
635-361-9
243973-20-8
Repr. 2; Acute Tox. 4; Eye Irrit. 2; STOT SE 3; Skin Sens. 1A
201-462-8
83-26-1
Acute Tox. 3; STOT RE 1
202-128-4
92-13-7
Acute Tox. 2
200-332-8
57-47-6
Acute Tox. 2
201-607-5
85-44-9
Acute Tox. 4; STOT SE 3; Skin Irrit. 2; Eye Dam. 1; Resp. Sens. 1; Skin Sens. 1
238-887-3
14816-18-3
Repr. 2; Acute Tox. 4; Skin Sens. 1
233-046-7
10025-87-3
Acute Tox. 2; STOT RE 1; Acute Tox. 4; Skin Corr. 1A
231-749-3
7719-12-2
Acute Tox. 2; STOT RE 2; Skin Corr. 1A
232-178-2
7789-60-8
Skin Corr. 1B; STOT SE 3
215-236-1
1314-56-3
Skin Corr. 1A
233-060-3
10026-13-8
Acute Tox. 2; Acute Tox. 4; STOT RE 2; Skin Corr. 1B
233-663-1
10294-56-1
Acute Tox. 4; Skin Corr. 1A
-
17169-61-8
Carc. 1A; STOT RE 1; Resp. Sens. 1; Skin Sens. 1
231-633-2
7664-38-2
Skin Corr. 1B
237-066-7
13598-36-2
Acute Tox. 4; Skin Corr. 1A
232-260-8
7803-51-2
Flam. Gas 1; Press. Gas; Acute Tox. 1; Skin Corr. 1B
236-116-5
13171-21-6
Muta. 2; Acute Tox. 2; Acute Tox. 3
-
5826-76-6
Acute Tox. 4
211-987-4
732-11-6
Repr. 2; Acute Tox. 4; Acute Tox. 3; STOT SE 1
200-870-3
75-44-5
Press. Gas; Acute Tox. 2; Skin Corr. 1B
213-423-2
947-02-4
Acute Tox. 1; Acute Tox. 2
218-996-2
2310-17-0
Acute Tox. 3; Acute Tox. 4; Skin Sens. 1
223-874-7
4104-14-7
Acute Tox. 1; Acute Tox. 2
206-052-2
298-02-2
Acute Tox. 1; Acute Tox. 2
200-242-9
55-68-5
Acute Tox. 3; STOT RE 1; Skin Corr. 1B
202-866-7
100-57-2
Acute Tox. 3; STOT RE 1; Skin Corr. 1B
200-532-5
62-38-4
Acute Tox. 3; STOT RE 1; Skin Corr. 1B
257-622-2
52033-74-6
Carc. 1B; Muta. 2; Acute Tox. 3; STOT RE 1; Eye Irrit. 2; Skin Irrit. 2; Skin Sens. 1
200-444-7
59-88-1
Carc. 1B; Muta. 2; Acute Tox. 3; STOT RE 1; Eye Irrit. 2; Skin Irrit. 2; Skin Sens. 1
248-259-0
27140-08-5
Carc. 1B; Muta. 2; Acute Tox. 3; STOT RE 1; Eye Irrit. 2; Skin Irrit. 2; Skin Sens. 1
202-873-5
100-63-0
Carc. 1B; Muta. 2; Acute Tox. 3; STOT RE 1; Eye Irrit. 2; Skin Irrit. 2; Skin Sens. 1
DPX-E6758
406-600-2
89392-03-0
Skin Sens. 1
204-557-2
122-60-1
Carc. 1B; Muta. 2; Acute Tox. 4; STOT SE 3; Skin Irrit. 2; Skin Sens. 1
CGI 819
423-340-5
162881-26-7
Skin Sens. 1A
219-997-0
2597-03-7
Acute Tox. 4
293-435-2
91079-47-9
Carc. 1B; Muta. 1B
The combination of phenols extracted, using isobutyl acetate, from the ammonia liquor condensed from the gas evolved in low-temperature (less than 700°C (1292°F)) destructive distillation of coal. It consists predominantly of a mixture of monohydric and dihydric phenols.
284-881-9
84988-93-2
Carc. 1B; Muta. 1B
201-004-7
77-09-8
Carc. 1B; Muta. 2; Repr. 2
203-632-7
108-95-2
Muta. 2; Acute Tox. 3; STOT RE 2; Skin Corr. 1B
310-154-3
121158-58-5
Repr. 1B; Skin Corr. 1C; Eye Dam. 1
640-104-9
210555-94-5
Repr. 1B; Skin Corr. 1C; Eye Dam. 1
701-107-1
1801269-77-1
Repr. 1B; Skin Corr. 1C; Eye Dam. 1
701-105-0
1801269-80-6
Repr. 1B; Skin Corr. 1C; Eye Dam. 1
616-100-8
74499-35-7
Repr. 1B; Skin Corr. 1C; Eye Dam. 1
218-892-7
2275-14-1
Acute Tox. 3
Residue from the distillation of crude phenanthrene boiling in the approximate range of 340°C to 420°C (644°F to 788°F). It consists predominantly of phenanthrene, anthracene and carbazole.
310-169-5
122070-78-4
Carc. 1B
A complex combination of hydrocarbons. It consists predominantly of aliphatic, alicyclic and aromatic hydrocarbons. It may also contain small amounts of nitrogen, oxygen and sulfur compounds. This category encompasses light, medium, and heavy petroleums, as well as the oils extracted from tar sands. Hydrocarbonaceous materials requiring major chemical changes for their recovery or conversion to petroleum refinery feedstocks such as crude shale oils, upgraded shale oils and liquid coal fuels are not included in this definition.
232-298-5
8002-05-9
Carc. 1B
A complex combination which consists primarily of hydrogen with various small amounts of methane, ethane, and propane.
271-750-6
68607-11-4
Press. Gas; Flam. Gas 1; Carc. 1A; Muta. 1B
The complex combination of hydrocarbons obtained in a hydrofiner-powerformer process and boiling in a range of approximately 27°C to 210°C (80°F to 410°F).
271-058-4
68514-79-4
Carc. 1B; Muta. 1B; Asp. Tox. 1
A complex combination of hydrocarbons produced by the distillation of crude oil. It consists of hydrocarbons having carbon numbers predominantly in the range of C3 through C7 and boiling in the range of approximately -40°C to 80°C (-40°F to 176°F).
270-704-2
68476-85-7
Press. Gas; Flam. Gas 1; Carc. 1A; Muta. 1B
A complex combination of hydrocarbons obtained by subjecting liquefied petroleum gas mix to a sweetening process to convert mercaptans or to remove acidic impurities. It consists of hydrocarbons having carbon numbers predominantly in the range of C3 through C7 and boiling in the range of approximately -40°C to 80°C (-40°F to 176°F).
270-705-8
68476-86-8
Press. Gas; Flam. Gas 1; Carc. 1A; Muta. 1B
A complex combination of hydrocarbons obtained by subjecting a liquified petroleum gas mix to a sweetening process to oxidize mercaptans or to remove acidic impurities. It consists predominantly of C4 saturated and unsaturated hydrocarbons.
295-463-0
92045-80-2
Press. Gas; Flam. Gas 1; Carc. 1A; Muta. 1B
A complex combination of hydrocarbons obtained as a semi-solid from dewaxing paraffinic residual oil. It consists predominantly of saturated crystalline and liquid hydrocarbons having carbon numbers predominantly greater than C25.
232-373-2
8009-03-8
Carc. 1B
A complex combination of hydrocarbons obtained by the treatment of petroleum petrolatum with silicic acid for the removal of trace polar constituents and impurities. It consists predominantly of saturated hydrocarbons having carbon numbers predominantly greater than C20.
308-150-1
97862-98-1
Carc. 1B
A complex combination of organic compounds, predominantly high molecular weight carboxylic acids, obtained by the air oxidation of petrolatum.
265-206-7
64743-01-7
Carc. 1B
A complex combination of hydrocarbons obtained as a semi-solid from dewaxed paraffinic residual oil treated with hydrogen in the presence of a catalyst. It consists predominantly of saturated microcrystalline and liquid hydrocarbons having carbon numbers predominantly greater than C20.
295-459-9
92045-77-7
Carc. 1B
A complex combination of hydrocarbons obtained by treatment of petrolatum with bleaching earth for the removal of traces of polar constituents and impurities. It consists predominantly of hydrocarbons having carbon numbers predominantly in the range of greater than C25.
309-706-6
100684-33-1
Carc. 1B
A complex combination of hydrocarbons obtained by the treatment of petroleum petrolatum with activated carbon for the removal of trace polar constituents and impurities. It consists predominantly of saturated hydrocarbons having carbon numbers predominantly greater than C20.
308-149-6
97862-97-0
Carc. 1B
A complex combination of hydrocarbons obtained when petrolatum is treated with Al2O3 to remove polar components and impurities. It consists predominantly of saturated, crystalline, and liquid hydrocarbons having carbon numbers predominantly greater than C25.
285-098-5
85029-74-9
Carc. 1B
600-765-6
106700-29-2
Acute Tox. 4; Skin Sens. 1
258-067-9
52645-53-1
Acute Tox. 4; Skin Sens. 1
206-397-9
335-67-1
Carc. 2; Repr. 1B; Lact.; Acute Tox. 4; STOT RE 1; Eye Dam. 1
217-179-8
1763-23-1
Carc. 2; Repr. 1B; STOT RE 1; Acute Tox. 4; Lact.
-
21049-39-8
Carc. 2; Repr. 1B; Lact.; Acute Tox. 4; STOT RE 1; Eye Dam. 1
206-801-3
375-95-1
Carc. 2; Repr. 1B; Lact.; Acute Tox. 4; STOT RE 1; Eye Dam. 1
206-798-9
375-85-9
Repr. 1B; STOT RE 1
253-718-3
37924-13-3
Acute Tox. 4; Eye Irrit. 2
231-512-4
7601-90-3
Ox. Liq. 1; Skin Corr. 1A
234-390-0
11138-47-9
Ox. Sol. 3; Repr. 1B; Acute Tox. 3; Acute Tox. 4; STOT SE 3; Eye Dam. 1
234-390-0
11138-47-9
Ox. Sol. 3; Repr. 1B; Acute Tox. 3; Acute Tox. 4; STOT SE 3; Eye Dam. 1
234-390-0
11138-47-9
Repr. 1B; Acute Tox. 4; STOT SE 3; Eye Dam. 1
234-390-0
11138-47-9
Ox. Sol. 3; Repr. 1B; Acute Tox. 4; STOT SE 3; Eye Dam. 1
234-390-0
11138-47-9
Ox. Sol. 3; Repr. 1B; Acute Tox. 4; STOT SE 3; Eye Dam. 1
234-390-0
11138-47-9
Repr. 1B; STOT SE 3; Eye Dam. 1
600-611-8
10486-00-7
Repr. 1B; Acute Tox. 4; STOT SE 3; Eye Dam. 1
600-611-8
10486-00-7
Repr. 1B; STOT SE 3; Eye Dam. 1
600-419-4
10332-33-9
Ox. Sol. 3; Repr. 1B; Acute Tox. 4; STOT SE 3; Eye Dam. 1
600-419-4
10332-33-9
Ox. Sol. 3; Repr. 1B; Acute Tox. 3; Acute Tox. 4; STOT SE 3; Eye Dam. 1
603-902-8
13517-20-9
Repr. 1B; STOT SE 3; Eye Dam. 1
603-902-8
13517-20-9
Repr. 1B; Acute Tox. 4; STOT SE 3; Eye Dam. 1
201-186-8
79-21-0
Flam. Liq. 3; Org. Perox. D; Acute Tox. 4; Skin Corr. 1A
-
-
B Bacteria and similar species
232-629-3
9001-75-6
Eye Irrit. 2; STOT SE 3; Skin Irrit. 2; Resp. Sens. 1
210-852-7
624-54-4
Flam. Liq. 3
207-332-7
463-04-7
Flam. Liq. 2; Acute Tox. 4
211-340-6
638-49-3
Flam. Liq. 3; Eye Irrit. 2; STOT SE 3
211-047-3
628-63-7
Flam. Liq. 3
215-320-8
1321-64-8
Acute Tox. 4; Eye Irrit. 2; Skin Irrit. 2
442-030-0
321912-47-4
Eye Dam. 1
414-910-4
-
Eye Dam. 1; Skin Sens. 1
OLIVE-GREEN JB 1170
419-210-2
178452-71-6
Eye Dam. 1
436-920-8
172399-10-9
Eye Dam. 1
301-312-2
93983-23-4
Eye Irrit. 2
REACTIVE NAVY BLUE 9411; SUMIFIX SUPRA MARINE BNF GRANULES
423-790-2
1379676-74-0
Eye Dam. 1; Skin Sens. 1
205-391-3
140-01-2
Repr. 1B; Acute Tox. 4; STOT RE 2
418-270-7
-
Skin Sens. 1
404-290-3
7216-95-7
Repr. 1B; Acute Tox. 4; STOT RE 2; Eye Irrit. 2
250-378-8
30899-19-5
Flam. Liq. 3; Acute Tox. 4; STOT SE 3
204-634-0
123-54-6
Flam. Liq. 3; Acute Tox. 4
203-692-4
109-66-0
Flam. Liq. 2; Asp. Tox. 1; STOT SE 3
202-490-3
96-22-0
Flam. Liq. 2; STOT SE 3
426-590-3
187412-41-5
Skin Sens. 1
222-540-8
3524-68-3
Eye Irrit. 2; Skin Irrit. 2; Skin Sens. 1
201-084-3
78-11-5
Expl. 1.1
201-084-3
78-11-5
Unst. Expl.
225-644-1
4986-89-4
Eye Irrit. 2; Skin Irrit. 2; Skin Sens. 1
201-778-6
87-86-5
Carc. 2; Acute Tox. 2; Acute Tox. 3; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2
200-925-1
76-01-7
Carc. 2; STOT RE 1
210-172-0
608-93-5
Flam. Sol. 1; Acute Tox. 4

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