EU-SAFETY_HEALTH_WORK-PREAMBLE

Safety and Health of Workers at Work Directive - Hazardous Substances

EU. Hazardous Substances for Purposes of Directive 89/391/EEC, 29 June 1989, amended by Regulation 1137/2008/EC, 21 November 2008 (Table 3/Annex VI, CLP; Annex III, 2000/54/EC)

This list contains a non-exhaustive inventory of substances that fall within the scope of the European Union's definition of hazardous chemical and biological substances, as provided on: (1) Table 3 of Annex VI to the CLP Regulation 1272/2008/EC; and (2) Annex III of Directive 2000/54/EC (Biological Agents). The EU's Occupational Safety and Health (OSH) Framework Directive 89/391/EEC applies to risks arising from chemical, physical and biological agents at the workplace.

Last updated 19 April 2024. Database contains 4691 unique substances/entries.

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Substance Name	EC No.	CAS No.	EU CLP (1272/2008)
9-(2-propenyloxy)tricyclo[5.2.1.0(2,6)]dec-3(or-4-)-ene FLEUROXENE	430-830-2	26912-64-1	Skin Irrit. 2
9,9-bis(4-hydroxyphenyl)fluorene BPFL; FLUOREN-BIS-PHENOL	406-950-6	3236-71-3	Eye Irrit. 2; Skin Irrit. 2
8-p-menthyl hydroperoxide; p-menthane hydroperoxide	201-281-4	80-47-7	Org. Perox. D; Skin Corr. 1B; Acute Tox. 4
8-azaspiro[4.5]decane-7,9-dione 3,3-TETRAMETHYLENE GLUTARIMIDE	427-770-4	1075-89-4	Acute Tox. 3
8-amino-7-methylquinoline 8-AMINO-7-METHYLCHINOLIN	412-760-4	5470-82-6	Acute Tox. 4; Skin Sens. 1
8,9-dinorborn-5-ene-2,3-dicarboxylic anhydride	620-411-4	123748-85-6	Acute Tox. 4; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2; Resp. Sens. 1
8,9,10-trinorborn-5-ene-2,3-dicarboxylic anhydride	204-957-7	129-64-6	Eye Dam. 1; Resp. Sens. 1; Skin Sens. 1
8,9,10-trinorborn-2-yl acrylate	-	10027-06-2	Acute Tox. 4; Skin Irrit. 2; Skin Sens. 1
8,8-dimethyl-7-isopropyl-6,10-dioxaspiro[4.5]decane OPALAL	424-030-2	62406-73-9	Skin Irrit. 2
7a-ethyl-3,5-bis(1-methylethyl)-2,3,4,5-tetrahydrooxazolo[3,4-c]-2,3,4,5-tetrahydrooxazole ZOLDINE RD-20	417-140-7	79185-77-6	Skin Irrit. 2
7-oxa-3-oxiranylbicyclo [4.1.0]heptane; 1,2-epoxy- 4-epoxyethylcyclohexane; 4-vinylcyclohexene diepoxide	203-437-7	106-87-6	Carc. 1B; Muta. 2; Repr. 1B; Acute Tox. 3; Acute Tox. 4
7-methylocta-1,6-diene 7-METHYL-1,6-OCTADIENE	404-210-7	42152-47-6	Flam. Liq. 3
7-methoxy-6-(3-morpholin-4-yl-propoxy)-3H-quinazolin-4-one [containing ≥ 0,5 % formamide (EC No 200-842-0)]	429-400-7	199327-61-2	Repr. 1B
7-chloro-1-cyclopropyl-6-fluoro-1,4-dihydro-4-oxoquinoline-3-carboxylic acid FLUORCHINOLONCARBONSÄURE	405-050-0	86393-33-1	Acute Tox. 4
7-amino-4-hydroxy-2-naphthalenesulfonic acid, coupled with 5 (or 8) -amino-8 (or 5)-[[4-[[4-[[4-amino-6(or 7)-sulfo-1-naphthyl]azo]phenyl]amino]-3-sulfophenyl]azo]-2-naphthalenesulfonic acid and 4-hydroxy-7-(phenylamino)-2-naphthalenesulfonic acid, sodium salt	424-850-0	189702-72-5	Eye Dam. 1
7-amino-3-((5-carboxymethyl-4- methyl-1,3-thiazol-2- ylthio)methyl)-8-oxo-5-thia-1- azabicyclo(4.2.0)oct-2-ene-2- carboxylic acid TACS	403-690-5	111298-82-9	Resp. Sens. 1; Skin Sens. 1
7-[((4,6-dichloro-1,3,5-triazin-2-yl)amino)-4-hydroxy-3-(4-((2-sulfoxy)ethyl)sulfonyl)phenylazo]naphthalene-2-sulfonic acid ORANGE BIREACTIVE DYE	407-050-6	117715-57-8	Skin Sens. 1
7,7-dimethyl-3-oxa-6-azaoctan-1-ol FLEXSORB-SE	400-390-6	87787-67-5	Skin Corr. 1A; Acute Tox. 4
7,7,9(or 7,9,9)-trimethyl-4,13-dioxo-3,14-dioxa-5,12-diazahexadecane-1,16-diyl bismethacrylate	276-957-5	72869-86-4	Skin Sens. 1B
6-phenyl-1,3,5-triazine-2,4- diyldiamine; 6-phenyl-1,3,5-triazine-2,4-diamine; benzoguanamine	202-095-6	91-76-9	Acute Tox. 4
6-methyl-2,4-bis(methylthio)phenylene-1,3-diamine DM-C-TDA; DMTDA; ETHACURE (R) 300 CURATIVE	403-240-8	106264-79-3	Acute Tox. 4; Skin Sens. 1
6-methoxy-m-toluidine; p-cresidine	204-419-1	120-71-8	Carc. 1B; Acute Tox. 4
6-hydroxyindole IMEXINE OBA	417-020-4	2380-86-1	Acute Tox. 4; Eye Dam. 1; Skin Sens. 1
6-hydroxy-1-(3-isopropoxypropyl)-4-methyl-2-oxo-5-[4-(phenylazo)phenylazo]-1,2-dihydro-3-pyridinecarbonitrile ARANCIO DISPERSO 149; C.I. DISPERSE ORANGE 149; DISPERS ORANGE 149; DISPERSE ORANGE 149; ORANGE DISPERSE 149; TERASIL GOLDGELB 2RS	400-340-3	85136-74-9	Carc. 1B
6-glycidyloxynapht-1-yl oxymethyloxirane	429-960-2	27610-48-6	Muta. 2; Acute Tox. 4; Skin Irrit. 2; Skin Sens. 1
6-fluoro-2-methyl-3-(4-methylthiobenzyl)indene IN-4; INDENE IN-4	405-410-7	41201-60-9	Skin Irrit. 2; Eye Dam. 1; Skin Sens. 1
6-ethyl-5-fluoro-4(3H)-pyrimidone UK-103,442	422-460-5	137234-87-8	Acute Tox. 4
6-docosyloxy-1-hydroxy-4-(1-(4-hydroxy-3-methylphenanthren-1-yl)-3-oxo-2-oxaphenalen-1-yl)naphthalene-2-carboxylic acid ENS 131	404-550-6	130263-41-1	Skin Sens. 1
6-dimethylaminohexan-1-ol AF-507; M-3181	404-680-3	1862-07-3	Acute Tox. 4; Skin Corr. 1B
6-[C12-18-alkyl-(branched, unsaturated)-2,5-dioxopyrrolidin-1-yl]hexanoic acid, sodium and tris(2-hydroxyethyl)ammonium salts	701-271-4	-	Repr. 1B; Eye Irrit. 2
6-[C12-18-alkyl-(branched, unsaturated)-2,5-dioxopyrrolidin-1-yl]hexanoic acid	701-162-1	-	Repr. 1B
6-[(C10-C13)-alkyl-(branched, unsaturated)-2,5-dioxopyrrolidin-1-yl]hexanoic acid	701-118-1	2156592-54-8	Repr. 1B; Eye Irrit. 2
6-(phthalimido)peroxyhexanoic acid PAP	410-850-8	128275-31-0	Org. Perox. D; Eye Dam. 1
6-(nonylamino)-6-oxo-peroxyhexanoic acid ELFADOX EN 3001	406-680-9	104788-63-8	Org. Perox. C; Eye Dam. 1; Skin Sens. 1
6-(2,3-dimethylmaleimido)hexyl methacrylate RONACAT RO 305; RONACOAT RO 305	404-870-6	63740-41-0	Skin Sens. 1
6-(1α,5aβ,8aβ,9-pentahydroxy-7β-isopropyl-2β,5β,8β-trimethylperhydro-8bα,9-epoxy-5,8-ethanocyclopenta[1,2-b]indenyl) pyrrole-2-carboxylate; ryania	239-732-2	15662-33-6	Acute Tox. 4
6,7-dihydrodipyrido[1,2-α:2',1'- c]pyrazinediylium dihydroxide	301-467-6	94021-76-8	Acute Tox. 2; STOT RE 1; Acute Tox. 4; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2; Skin Sens. 1
6,6'-di-tert-butyl-2,2'-methylenedi-p-cresol; [DBMC]	204-327-1	119-47-1	Repr. 1B
6,6'-bis(diazo-5,5', 6,6'-tetrahydro-5,5'-dioxo)[methylene-bis(5-(6-diazo-5,6-dihydro-5-oxo-1-naphthylsulphonyloxy)-6-methyl-2-phenylene]di(naphthalene-1-sulfonate)	441-550-5	-	Self-react. C; Carc. 2
6,13-dichloro-3,10-bis{2-[4-fluoro-6-(2-sulfophenylamino)-1,3,5-triazin-2-ylamino]propylamino}benzo[5,6][1,4]oxazino[2,3-.b.]phenoxazine-4,11-disulphonic acid, lithium-, sodium salt BLEU REN 20	418-000-8	163062-28-0	Eye Dam. 1
5-{4-[5-amino-2-[4-(2-sulfoxyethylsulfonyl)phenylazo]-4-sulfo-phenylamino]-6-chloro-1,3,5-triazin-2-ylamino}-4-hydroxy-3-(1-sulfo-naphthalen-2-ylazo)-naphthalene-2,7-disulfonicacid sodium salt ROUGE TZ 4075	418-340-7	157707-94-3	Eye Dam. 1
5-thiazolylmethanol A-87440.0; A-87440.00	414-780-9	38585-74-9	Eye Dam. 1
5-tert-butyl-3-isoxazolylamine hydrochloride BISOX HCL	404-840-2	164578-13-6	Acute Tox. 4; STOT RE 2; Eye Dam. 1
5-nitroacenaphthene	210-025-0	602-87-9	Carc. 1B
5-nitro-o-toluidine hydrochloride	256-960-8	51085-52-0	Carc. 2; Acute Tox. 3
5-nitro-o-toluidine	202-765-8	99-55-8	Carc. 2; Acute Tox. 3
5-methylpyrazine-2-carboxylic acid 5-METHYLPYRAZINE-2-CARBOXYLIC ACID; ACIDO 5-METILPIRAZIN CARBOSSILICO	413-260-9	5521-55-1	Eye Dam. 1
5-methylhexan-2-one; isoamyl methyl ketone	203-737-8	110-12-3	Flam. Liq. 3; Acute Tox. 4
5-methylheptan-3-one	208-793-7	541-85-5	Flam. Liq. 3; Eye Irrit. 2; STOT SE 3
5-fluoro-1,3-dimethyl-N-[2-(4-methylpentan-2-yl)phenyl]-1H-pyrazole-4-carboxamide; 2'-[(RS)-1,3-dimethylbutyl]-5-fluoro-1,3-dimethylpyrazole-4-carboxanilide; penflufen	619-823-7	494793-67-8	Carc. 2
5-ethyl-2,4-dihydro-4-(2-phenoxyethyl)-3H-1,2,4-triazol-3-one	414-470-3	95885-13-5	Acute Tox. 4
5-ethoxy-5H-furan-2-one	428-330-4	2833-30-9	Skin Corr. 1B; Acute Tox. 4; STOT RE 2; Skin Sens. 1
5-endo-hexyl-bicyclo[2.2.1]hept-2-ene	435-000-3	22094-83-3	Asp. Tox. 1; Skin Irrit. 2
5-chloro-2-(4-chlorophenoxy)phenol	429-290-0	3380-30-1	Eye Dam. 1
5-chloro-2,3-difluoropyridine CDFP	410-090-7	89402-43-7	Flam. Liq. 3; Acute Tox. 4
5-chloro-1,3-dihydro-2H-indol-2-one CP-13,853	412-200-9	17630-75-0	Repr. 2; Acute Tox. 4; Skin Sens. 1
5-bromo-8-naphtholactam FAT 92'374	413-480-5	24856-00-6	Acute Tox. 4; Skin Sens. 1
5-amino-6-methyl-1,3-dihydrobenzoimidazol-2-one	428-410-9	67014-36-2	Acute Tox. 4; Skin Sens. 1
5-amino-2,4,6-triiodo-1,3-benzenedicarbonyldichloride ATIPACL	417-220-1	37441-29-5	Skin Sens. 1
5-acetyl-3-amino-10,11-dihydro-5H-dibenz[b, f]azepine-hydrochloride 5-ACETYL-3-AMINO-IMINODIBENZYL.HCL	410-490-1	138451-65-7	Acute Tox. 4; STOT RE 2; Eye Dam. 1; Skin Sens. 1
5-acetoxy-2-(R, S)butyryloxymethyl-1,3-oxathiolane	433-530-1	143446-73-5	Acute Tox. 4; Skin Sens. 1
5-[[4-chloro-6-[[2-[[4-fluoro-6-[[5-hydroxy-6-[(4-methoxy-2-sulfophenyl)azo]-7-sulfo-2-naphthalenyl]amino]-1,3,5-triazin-2-yl]amino]-1-methylethyl]amino]-1,3,5-triazin-2-yl]amino]-3-[[4-(ethenylsulfonyl)phenyl]azo]-4-hydroxy-naphtalene-2,7-disulfonic acid, sodium salt ROUGE REACTIF REN 208	418-380-5	168113-78-8	Eye Dam. 1
5-(4-[4-[4-(3,5-dicarboxy-phenyl-azo)phenylamino]-6-morpholin-4-yl-1,3,5-triazin-2-ylamino]phenylazo)isophthalic acid, mixed monosodium and diammonium salt	414-410-6	1379676-83-1	Eye Dam. 1; Skin Sens. 1
5-(3,6,9-trioxa-2-undecy loxy)benzo(d)-1,3-dioxolane; sesamex	-	51-14-9	Acute Tox. 4
5-(2-bromophenyl)-2-tert-butyl-2H-tetrazole WAY-128170	420-820-6	153042-18-3	Flam. Liq. 3; Acute Tox. 4
5-(2-amino-5-cyano-6-[2-(2-hydroxyethoxy)ethylamino]-4-methylpyridin-3-ylazo)-3-methyl-2,4-dicarbonitrilethiophene	410-530-8	107815-88-3	Skin Sens. 1
5-(2,4-dioxo-1,2,3,4-tetrahydropyrimidine)-3-fluoro-2-hydroxymethyltetrahydrofuran 123U83; DDFU	415-360-8	41107-56-6	Muta. 2
5,6-dihydroxyindole IMEXINE OAY	412-130-9	3131-52-0	Acute Tox. 4; Eye Dam. 1
5,6-dihydroxy-2,3-dihydro-1H-indolium bromide	421-170-6	138937-28-7	Acute Tox. 4; Eye Dam. 1
5,6-dihydro-3H-imidazo[2,1-c]-1,2,4-dithiazole-3-thione; etem	251-684-4	33813-20-6	Acute Tox. 4
5,6,12,13-tetrachloroanthra(2,1,9-def:6,5,10-d'e'f')diisoquinoline-1,3,8,10(2H,9H)-tetrone PIGMENTROT 1017; SUBSTANCE H112287	405-100-1	115662-06-1	Repr. 2
5,5-dimethyl-perhydro-pyrimidin-2-one α-(4-trifluoromethylstyryl)-α-(4-trifluoromethyl)cinnamylidenehydrazone HYDRAMETHYLNON	405-090-9	67485-29-4	STOT RE 1; Acute Tox. 4; Eye Irrit. 2
5,5-dimethyl-3-oxocyclohex-1-enyl dimethylcarbamate 5,5-dimethyldihydroresorcinol dimethylcarbamate; dimetan	204-525-8	122-15-6	Acute Tox. 3
5(or 6)-tert-butyl-2'-chloro-6'-ethylamino-3',7'-dimethylspiro(isobenzofuran-1(1H),9'-xanthene)-3-one R-GELB 2454	400-680-2	98181-47-6	Acute Tox. 4
4H-3,1-benzoxazine-2,4(1H)-dione	204-255-0	118-48-9	Eye Irrit. 2; Skin Sens. 1
4-{[(6-chloropyridin-3-yl)methyl](2,2-difluoroethyl)amino}furan-2(5H)-one; flupyradifurone	804-373-8	951659-40-8	Acute Tox. 4; STOT RE 2
4-vinylcyclohexene	202-848-9	100-40-3	Carc. 2
4-tert-butylphenol	202-679-0	98-54-4	Repr. 2; Skin Irrit. 2; Eye Dam. 1
4-tert-butylbenzoic acid	202-696-3	98-73-7	Repr. 1B; STOT RE 1; Acute Tox. 4
4-propylcyclohexanone BICH-3 STUFE 3	406-810-4	40649-36-3	Skin Irrit. 2
4-phenylbut-1-ene 4-PHENYL-1-BUTENE; SQ 31,175; SQ31175	405-980-7	768-56-9	Skin Irrit. 2
4-oxo-4-(p-tolyl)butyric acid adduct with 4-ethylmorpholine	419-240-6	171054-89-0	Eye Dam. 1
4-o-tolylazo-o-toluidine; 4-amino-2',3-dimethylazobenzene; fast garnet GBC base; AAT; o-aminoazotoluene	202-591-2	97-56-3	Carc. 1B; Skin Sens. 1
4-nonylphenol, reaction products with formaldehyde and dodecane-1-thiol POLYSTAY K; WINGSTAY K	404-160-6	164907-73-7	Skin Sens. 1
4-nonylphenol, branched	284-325-5	84852-15-3	Repr. 2; Acute Tox. 4; Skin Corr. 1B
4-nitrotoluene	202-808-0	99-99-0	Acute Tox. 3; STOT RE 2
4-nitrosophenol	203-251-6	104-91-6	Muta. 2; Acute Tox. 4; Eye Dam. 1
4-nitrosomorpholine	627-564-6	59-89-2	Carc. 1B; Muta. 2; STOT RE 1
4-nitrosoaniline	211-535-6	659-49-4	Acute Tox. 4
4-nitrophenol; p-nitrophenol	202-811-7	100-02-7	Acute Tox. 4; STOT RE 2
4-nitrobiphenyl	202-204-7	92-93-3	Carc. 1B
4-methylpyridine; 4-picoline	203-626-4	108-89-4	Flam. Liq. 3; Acute Tox. 3; Acute Tox. 4; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2
4-methylpentan-2-one; isobutyl methyl ketone	203-550-1	108-10-1	Flam. Liq. 2; Carc. 2; Acute Tox. 4; Eye Irrit. 2; STOT SE 3
4-methylpentan-2-ol; methyl isobutyl carbinol	203-551-7	108-11-2	Flam. Liq. 3; STOT SE 3
4-methylpent-3-en-2-one; mesityl oxide	205-502-5	141-79-7	Flam. Liq. 3; Acute Tox. 4
4-methylimidazole	212-497-3	822-36-6	Carc. 1B; Repr. 1B
4-methylheptane	209-650-1	589-53-7	Flam. Liq. 2; Asp. Tox. 1; Skin Irrit. 2; STOT SE 3
4-methyl-N-(methylsulfonyl)benzenesulfonamide POWDERLINK (R) MTSI	415-040-8	14653-91-9	Acute Tox. 4; STOT SE 3; Eye Dam. 1
4-methyl-m-phenylenediamine; 2,4-toluenediamine	202-453-1	95-80-7	Carc. 1B; Muta. 2; Repr. 2; Acute Tox. 3; Acute Tox. 4; STOT RE 2; Skin Sens. 1
4-methyl-m-phenylene diisocyanate; toluene-2,6-di-isocyanate	209-544-5	584-84-9	Carc. 2; Acute Tox. 2; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2; Resp. Sens. 1; Skin Sens. 1
4-methyl-8-methylenetricyclo[3.3.1.13,7]dec-2-yl acetate PRISMYLATE	406-560-6	122760-85-4	Skin Irrit. 2; Skin Sens. 1
4-methyl-8-methylenetricyclo[3.3.1.1 3,7]decan-2-ol PRISMANTOL	406-330-5	122760-84-3	Skin Irrit. 2; Skin Sens. 1
4-methyl-3-oxo-N-phenyl-2-(phenylmethylene)pentanamide	425-860-8	125971-57-5	Skin Sens. 1
4-methoxy-N,6-dimethyl-1,3,5- triazin-2-ylamine 2-METHOXY-4-METHYL-6-METHYLAMINO-1,3,5-TRIAZIN; DPX-L5296; L5296	401-360-5	5248-39-5	Acute Tox. 4; STOT RE 2
4-methoxy-4-methylpentan-2-one	203-512-4	107-70-0	Flam. Liq. 3; Acute Tox. 4
4-mesyl-2-nitrotoluene	430-550-0	1671-49-4	Repr. 2; Acute Tox. 4; Skin Sens. 1
4-isocyanatosulphonyltoluene; tosyl isocyanate	223-810-8	4083-64-1	Eye Irrit. 2; STOT SE 3; Skin Irrit. 2; Resp. Sens. 1
4-hydroxy-7-(2-aminoethyl)-1,3-benzothiazol-2(3H)-one hydrochloride	432-470-1	189012-93-9	Eye Dam. 1; Skin Sens. 1
4-hydroxy-4-methylpentan-2-one; diacetone alcohol	204-626-7	123-42-2	Eye Irrit. 2
4-hydroxy-3-(3-(4'-bromo-4-biphenylyl)-1,2,3,4-tetrahydro-1-naphthyl)coumarin; brodifacoum	259-980-5	56073-10-0	Repr. 1A; Acute Tox. 1; STOT RE 1
4-hexadecyl-1-phenylpyrazolidin-3-one	430-840-7	202483-63-4	Skin Sens. 1
4-formylphenylboronic acid	438-670-5	87199-17-5	Skin Sens. 1
4-fluoro-3-trifluoromethylphenol	432-560-0	61721-07-1	Acute Tox. 4; Skin Corr. 1A; Skin Sens. 1
4-ethylamino-3-nitrobenzoic acid RO 827	412-090-2	2788-74-1	Acute Tox. 4; Skin Sens. 1
4-ethyl-2-methyl-2-isopentyl-1,3-oxazolidine ZOLDINE (R) MS-52	410-470-2	137796-06-6	Skin Corr. 1B; Skin Sens. 1
4-ethoxyaniline; p-phenetidine	205-855-5	156-43-4	Muta. 2; Acute Tox. 4; Eye Irrit. 2; Skin Sens. 1
4-dimethylaminobenzenediazonium 3-carboxy-4-hydroxybenzenesulfonate DIAZO-A-SALICYLSULFONATE	404-980-4	124737-31-1	Self-react. C; Acute Tox. 3; Acute Tox. 4; STOT RE 2; Eye Dam. 1; Skin Sens. 1
4-dichloroacetyl-1-oxa-4-azaspiro[4.5]decane	401-130-4	71526-07-3	Skin Sens. 1
4-cyclohexyl-2-methyl-2-butanol CORANOL	420-630-3	83926-73-2	Eye Dam. 1
4-CPA (ISO); 4-chlorophenoxyacetic acid	204-581-3	122-88-3	Acute Tox. 4
4-chlorotoluene	203-397-0	106-43-4	Acute Tox. 4
4-chlorophenylisocyanate	203-176-9	104-12-1	Acute Tox. 2; Acute Tox. 4; STOT SE 3; Skin Irrit. 2; Eye Dam. 1; Resp. Sens. 1
4-chlorophenyl cyclopropyl ketone O-(4-aminobenzyl)oxime ACC ETHER	405-260-2	94050-51-8	Acute Tox. 4; Skin Sens. 1
4-chlorophenol	203-402-6	106-48-9	Acute Tox. 4
4-chlorobutyl veratrate CHLORO ESTER; CHLOROESTER	410-950-1	69788-75-6	Skin Sens. 1
4-chloroaniline	203-401-0	106-47-8	Carc. 1B; Acute Tox. 3; Skin Sens. 1
4-chloro-o-toluidine hydrochloride	221-627-8	3165-93-3	Carc. 1B; Muta. 2; Acute Tox. 3
4-chloro-o-toluidine	202-441-6	95-69-2	Carc. 1B; Muta. 2; Acute Tox. 3
4-chloro-o-cresol; 4-chloro-2-methylphenol	216-381-3	1570-64-5	Acute Tox. 3; Skin Corr. 1A
4-chloro-3,5-dimethylphenol	201-793-8	88-04-0	Acute Tox. 4; Eye Irrit. 2; Skin Irrit. 2; Skin Sens. 1
4-bromo-2-chlorofluorobenzene 4-BROM-2-CHLORFLUORBENZOL; 4-BROMO-2-CHLOROFLUOROBENZENE	405-580-2	60811-21-4	Acute Tox. 4; Skin Irrit. 2
4-benzyl-2,6-dihydroxy-4-aza-heptylene bis (2,2-dimethyloctanoate) VMZ95005	418-100-1	172964-15-7	Skin Sens. 1
4-aminophenol	204-616-2	123-30-8	Muta. 2; Acute Tox. 4
4-aminoazobenzene; 4-phenylazoaniline	200-453-6	60-09-3	Carc. 1B
4-amino-N,N-dimethylaniline; 3-amino-N,N'-dimethylaniline	202-807-5	99-98-9	Acute Tox. 3
4-amino-N,N-diethylaniline; N,N-diethyl-p-phenylendiamine	202-214-1	93-05-0	Acute Tox. 3; Skin Corr. 1B
4-amino-3-fluorophenol FAP	402-230-0	399-95-1	Carc. 1B; Acute Tox. 4; Skin Sens. 1
4-amino-3-[[4-[[2-(sulfooxy)ethyl]sulfonyl]phenyl]azo]-1-naphthalene sulfonic acid	427-680-5	188907-52-0	Eye Dam. 1; Skin Sens. 1
4-amino-2-(aminomethyl)phenol dihydrochloride OXAMITOL	412-510-4	135043-64-0	Acute Tox. 4; Skin Sens. 1
4-[N-ethyl-N-(2-hydroxyethyl)amino]-1-(2-hydroxyethyl)amino-2-nitrobenzene, monohydrochloride NITROBLAU; NITROBLUE	407-020-2	132885-85-9	Acute Tox. 4; Skin Sens. 1
4-[4-amino-5-hydroxy-3-(4-(2-sulfoxyethylsulfonyl)phenylazo)-2,7-disulfonapht-6-ylazo]-6-[3-(4-amino-5-hydroxy-3-(4-(2-sulfoxyethylsulfonyl)phenylazo)-2,7-disulfonapht-6-ylazo]phenylcarbonylamino]benzenesulfonic acid, sodium salt NAVY DER 7850	417-640-5	161935-19-9	Eye Dam. 1; Skin Sens. 1
4-[4-(2-ethylhexyloxy)phenyl](1,4-thiazinane-1,1-dioxide) CIN 10097929	418-320-8	133467-41-1	Acute Tox. 4
4-[4-(2,2-dimethyl-propanamido)]phenylazo-3-(2-chloro-5-(2-(3-pentadecylphenoxy)butylamido)anilino)-1-(2,4,6-trichlorophenyl)-2-pyrazoline-5-one	420-220-4	92771-56-7	Skin Sens. 1
4-[4-(1,3-dihydroxyprop-2-yl)phenylamino]-1,8-dihydroxy-5-nitroanthraquinone ANTHRACHINON BLAU 27 HD	406-057-1	114565-66-1	Carc. 2; Skin Sens. 1
4-[3-(diethoxymethylsilylpropoxy)-2,2,6,6-tetramethyl]piperidine PSL 6	411-400-3	102089-33-8	Acute Tox. 4; STOT RE 2; Skin Irrit. 2; Eye Dam. 1
4-[2-(1-methyl-2-(4-morpholinyl)ethoxy)ethyl]morpholine M.E.M.P.E.	407-940-4	111681-72-2	Eye Dam. 1
4-[(3-hydroxypropyl)amino]-3-nitrophenol PLAKATROT Z; ROT BN	406-305-9	92952-81-3	Skin Irrit. 2
4-[(3-chlorophenyl)(1H-imidazol-1-yl)methyl]-1,2-benzenediamine dihydrochloride	425-030-5	159939-85-2	Repr. 2; Acute Tox. 4; Skin Corr. 1B; Skin Sens. 1
4-(trans-4-propylcyclohexyl)acetophenone 4-(4-PROPYLCYCLOHEXYL)-ACETOPHENON	406-700-6	78531-61-0	Skin Sens. 1
4-(cyanomethyl)-4-methylmorpholin-4-ium hydrogen sulfate	431-200-1	208538-34-5	Acute Tox. 4; Eye Dam. 1; Skin Sens. 1
4-(5-(5-[1-(4-carboxyphenyl)hexahydro-2,4,6-trioxopyrimidin-5-ylidene]penta-1,3-dienyl)-1,2,3,4-tetrahydro-6-hydroxy-2,4-dioxopyrimidin-1-yl)benzoic acid-triethylamine salt	426-900-7	203118-12-1	STOT SE 3
4-(4-tolyloxy)biphenyl JKY-120	405-730-7	51601-57-1	STOT RE 2
4-(4-nitrophenylazo)-2,6-di-sec-butyl-phenol MORTRACE SB CONC.	410-610-2	111850-24-9	STOT RE 2; Eye Irrit. 2; Skin Irrit. 2; Skin Sens. 1
4-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1-carbaldehyde	250-863-4	31906-04-4	Skin Sens. 1A
4-(4-aminophenyl)aniline;sulfuric acid	208-520-1	531-86-2	Carc. 1A; Acute Tox. 4
4-(4-aminophenyl)aniline;dihydrochloride	208-519-6	531-85-1	Carc. 1A; Acute Tox. 4
4-(4-amino-3-methylphenyl)-2-methylaniline;sulfuric acid	277-985-0	74753-18-7	Carc. 1B; Acute Tox. 4
4-(4-amino-3-methylphenyl)-2-methylaniline;dihydrochloride	210-322-5	612-82-8	Carc. 1B; Acute Tox. 4
4-(4,4-dimethyl-3-oxo-pyrazolidin-1-yl)-benzoic acid CARBODIM	413-120-7	107144-30-9	Acute Tox. 4
4-(3,4-dichlorophenylazo)-2,6-di-sec-butyl-phenol MORTRACE ST CONC.	410-600-8	124719-26-2	STOT RE 2; Skin Irrit. 2
4-(2-methylacryloyloxy)phenyl4-allyloxybenzoate 4-ALLYLOXYBENZOESÄURE-(4-METHACRYLOYL)PHENYLESTER	429-000-2	159235-16-2	Skin Sens. 1
4-(2-cyano-3-phenylamino acryloyloxymethyl)-cyclohexyl-methyl 2-cyano-3-phenylamino)-acrylate LICHTSCHUTZMITTEL 1071	413-510-7	147374-67-2	STOT RE 2; Skin Sens. 1
4-(2-chloro-4-trifluoromethyl)phenoxy-2-fluoroaniline hydrochloride WL 125892	402-190-4	113674-95-6	STOT RE 1; Acute Tox. 4; STOT RE 2; Eye Dam. 1; Skin Sens. 1
4-(1-oxo-2-propenyl)-morpholine ACRYLOYLMORPHOLIN	418-140-1	5117-12-4	Acute Tox. 4; STOT RE 2; Eye Dam. 1; Skin Sens. 1
4-(1,4-dioxa-spiro[4.5]dec-8-yl)-cyclohexanone	423-860-2	56309-94-5	Skin Sens. 1
4-(1,1,3,3-tetramethylbutyl)phenol; 4-tert-octylphenol	205-426-2	140-66-9	Skin Irrit. 2; Eye Dam. 1
4-(1(or 4 or 5 or 6)-methyl-8,9,10-trinorborn-5-en-2- yl)pyridine, reaction mass of isomers ORRINIFF	402-520-7	125352-06-9	Acute Tox. 4; Skin Irrit. 2; Skin Sens. 1
4,8,12-trimethyltrideca-3,7,11-trienoic acid, mixed isomers HOMOFARNESYLSÄURE	403-000-2	91853-67-7	Skin Irrit. 2
4,5-dichloro-2-octyl-2H-isothiazol-3-one; [DCOIT]	264-843-8	64359-81-5	Acute Tox. 2; Acute Tox. 4; Skin Corr. 1; Eye Dam. 1; Skin Sens. 1A
4,4-isobutylethylidenediphenol AP-5	401-720-1	6807-17-6	Repr. 1B; Eye Irrit. 2
4,4-dimethyl-3,5,8-trioxabicyclo[5.1.0]octane TRIOXABICYCLOOCTAN; TRIOXABICYCLOOCTANE	421-750-9	57280-22-5	Eye Irrit. 2; Skin Sens. 1
4,4-dimethoxybutylamine AMINOBUTYRALDEHYDE DIMETHYL ACETAL	407-690-6	19060-15-2	Acute Tox. 4; Skin Corr. 1B; Skin Sens. 1
4,4,5,5-tetrachloro-1,3-dioxolan-2-one CARBONATE DE TETRACHLOROETHYLENE	404-060-2	22432-68-4	Acute Tox. 2; Acute Tox. 4; Skin Corr. 1B
4,4,5,5,5-pentafluoropentan-1-ol	421-360-9	148043-73-6	Acute Tox. 4
4,4'-thiodianiline and its salts	205-370-9	139-65-1	Carc. 1B; Acute Tox. 4
4,4'-thiodi-o-cresol HMPSC	403-330-7	24197-34-0	Eye Dam. 1
4,4'-sulphonyldiphenol; bisphenol S	201-250-5	80-09-1	Repr. 1B
4,4'-oxydianiline and its salts show/hide 4,4'-oxydianiline EC / List no: 202-977-0 \| CAS no: 101-80-4	-	-	Carc. 1B; Muta. 1B; Repr. 2; Acute Tox. 3
4,4'-oxydi(benzenesulphonohydrazide)	201-286-1	80-51-3	Self-react. D
4,4'-oxybis(ethylenethio)diphenol DD-63	404-590-4	90884-29-0	Skin Sens. 1
4,4'-oxybis(benzenesulfonylazide)	431-850-4	7456-68-0	Expl. 1.1; STOT RE 2
4,4'-methylenediphenyl diisocyanate; diphenylmethane-4,4'-diisocyanate	202-966-0	101-68-8	Carc. 2; Acute Tox. 4; STOT RE 2; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2; Resp. Sens. 1; Skin Sens. 1
4,4'-methylenedi-o-toluidine	212-658-8	838-88-0	Carc. 1B; Acute Tox. 4; Skin Sens. 1
4,4'-methylenedi(cyclohexyl isocyanate); dicyclohexylmethane-4,4'-di-isocyanate	225-863-2	5124-30-1	Acute Tox. 3; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2; Resp. Sens. 1; Skin Sens. 1
4,4'-methylenebis(N,N'-dimethylcyclohexanamine) LUPRAGEN VP 9199 X	412-840-9	13474-64-1	Acute Tox. 4; STOT RE 2; Skin Corr. 1A
4,4'-methylenebis(2-isopropyl-6-methylaniline) LONZACURE M-MIPA	415-150-6	16298-38-7	STOT RE 2
4,4'-methylenebis(2-ethylaniline); 4,4'-methylenebis(2-ethylbenzeneamine)	243-420-1	19900-65-3	Carc. 2; Acute Tox. 4
4,4'-methylenebis(2,6-dimethylphenyl cyanate) AROCY M-10	405-790-4	101657-77-6	Skin Sens. 1
4,4'-methylene bis(3-chloro-2,6-di-ethylphenylisocyanate)	420-530-1	177027-34-8	Resp. Sens. 1; Skin Sens. 1
4,4'-ethylidenediphenyl dicyanate AROCY L-10	405-740-1	47073-92-7	Acute Tox. 4; STOT RE 2; Eye Dam. 1
4,4'-diaminodiphenylmethane; 4,4'-methylenedianiline	202-974-4	101-77-9	Carc. 1B; Muta. 2; STOT SE 1; STOT RE 2; Skin Sens. 1
4,4'-diamino-2-methylazobenzene ZP-DK 2115	407-590-2	43151-99-1	Acute Tox. 3; STOT RE 2; Skin Sens. 1
4,4'-carbonimidoylbis[N, N-dimethylaniline]	207-762-5	492-80-8	Carc. 2; Acute Tox. 4; Eye Irrit. 2
4,4'-bis(N-carbamoyl-4-methylbenzenesulfonamide)diphenylmethane B-TUM	418-770-5	151882-81-4	Carc. 2
4,4'-bis(dimethylamino)benzophenone; Michler's ketone	202-027-5	90-94-8	Carc. 1B; Muta. 2; Eye Dam. 1
4,4'-bi-o-toluidine	204-358-0	119-93-7	Carc. 1B; Acute Tox. 4
4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene] diphenol; bisphenol AF	216-036-7	1478-61-1	Repr. 1B
4,4'-(oxy-(bismethylene))-bis-1,3-dioxolane DIGLYCERINDIFORMAL (DGDF)	423-230-7	56552-15-9	Eye Dam. 1
4,4'-(4-iminocyclohexa-2,5-dienylidenemethylene)dianiline hydrochloride; C.I. Basic Red 9	209-321-2	569-61-9	Carc. 1B
4,4'-(1,3-phenylene-bis(1-methylethylidene))bis-phenol	428-970-4	13595-25-0	Repr. 2; Skin Sens. 1

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EU-SAFETY_HEALTH_WORK-PREAMBLE

EU-SAFETY_HEALTH_WORK-PREAMBLE

Safety and Health of Workers at Work Directive - Hazardous Substances

EU. Hazardous Substances for Purposes of Directive 89/391/EEC, 29 June 1989, amended by Regulation 1137/2008/EC, 21 November 2008 (Table 3/Annex VI, CLP; Annex III, 2000/54/EC)

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Last updated 19 April 2024. Database contains 4691 unique substances/entries.

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