EU-SAFETY_HEALTH_WORK-PREAMBLE

Safety and Health of Workers at Work Directive - Hazardous Substances

EU. Hazardous Substances for Purposes of Directive 89/391/EEC, 29 June 1989, amended by Regulation 1137/2008/EC, 21 November 2008 (Table 3/Annex VI, CLP; Annex III, 2000/54/EC)

This list contains a non-exhaustive inventory of substances that fall within the scope of the European Union's definition of hazardous chemical and biological substances, as provided on: (1) Table 3 of Annex VI to the CLP Regulation 1272/2008/EC; and (2) Annex III of Directive 2000/54/EC (Biological Agents). The EU's Occupational Safety and Health (OSH) Framework Directive 89/391/EEC applies to risks arising from chemical, physical and biological agents at the workplace.

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Last updated 25 April 2024. Database contains 4691 unique substances/entries.
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Substance Name
EC No.
CAS No.
EU CLP (1272/2008)
EU_BA Directive 2000/54/EC
1,1,2,2-tetrabromoethane
201-191-5
79-27-6
Acute Tox. 2; Eye Irrit. 2
fenamiphos (ISO); ethyl-4-methylthio-m-tolyl isopropyl phosphoramidate
244-848-1
22224-92-6
Acute Tox. 2; Eye Irrit. 2
fenbutatin oxide (ISO); bis(tris(2-methyl-2-phenylpropyl)tin)oxide
236-407-7
13356-08-6
Acute Tox. 2; Eye Irrit. 2; Skin Irrit. 2
colecalciferol; cholecalciferol; Vitamin D3
200-673-2
67-97-0
Acute Tox. 2; STOT RE 1
diphacinone (ISO); 2-diphenylacetylindan-1,3-dione
201-434-5
82-66-6
Acute Tox. 2; STOT RE 1
6,7-dihydrodipyrido[1,2-α:2',1'- c]pyrazinediylium dihydroxide
301-467-6
94021-76-8
Acute Tox. 2; STOT RE 1; Acute Tox. 4; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2; Skin Sens. 1
diquat dibromide
201-579-4
85-00-7
Acute Tox. 2; STOT RE 1; Acute Tox. 4; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2; Skin Sens. 1
diquat dichloride
223-714-6
4032-26-2
Acute Tox. 2; STOT RE 1; Acute Tox. 4; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2; Skin Sens. 1
phosphoryl trichloride
233-046-7
10025-87-3
Acute Tox. 2; STOT RE 1; Acute Tox. 4; Skin Corr. 1A
tolylfluanid (ISO);dichloro-N-[(dimethylamino)sulphonyl]fluoro-N-(p-tolyl)methanesulphenamide;[containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];tolylfluanid (ISO);dichloro-N-[(dimethylamino)sulphonyl]fluoro-N-(p-tolyl)methanesulphenamide;[containing ≥0.1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
211-986-9
731-27-1
Acute Tox. 2; STOT RE 1; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2; Skin Sens. 1
dithallium sulphate; thallic sulphate
231-201-3
7446-18-6
Acute Tox. 2; STOT RE 1; Skin Irrit. 2
thallium
231-138-1
7440-28-0
Acute Tox. 2; STOT RE 2
thallium compounds, with the exception of those specified elsewhere in this Annex
show/hide
Thallium(1+) propan-2-olate EC / List no: 254-386-2 | CAS no: 39262-04-9
Niobium thallium trioxide EC / List no: 235-634-9 | CAS no: 12396-77-9
Oxalic acid dithallium(I) salt EC / List no: 680-447-1 | CAS no: 30737-24-7
Trimethyl thallium EC / List no: - | CAS no: 3003-15-4
Thallium trinitrate EC / List no: 237-325-4 | CAS no: 13746-98-0
Thallium phosphate EC / List no: 257-461-8 | CAS no: 51833-34-2
Silver thallium dinitrate EC / List no: 247-283-9 | CAS no: 25822-21-3
Leach residues, zinc refining flue dust, cadmium-thallium ppt.
Sponge produced by leaching and precipitating cadmium and thallium fumes and flue dusts from lead/zinc smelting operations.
EC / List no: 296-097-4 | CAS no: 92257-11-9
Thallium iodate EC / List no: 238-831-8 | CAS no: 14767-09-0
Slimes and Sludges, thallium carbonate EC / List no: - | CAS no: 69029-96-5
Dithallium telluride EC / List no: 234-916-9 | CAS no: 12040-13-0
Thallium hydroxide EC / List no: 234-708-8 | CAS no: 12026-06-1
Sulfuric acid, thallium(3+) salt (2:1), dihydrate EC / List no: - | CAS no: 87963-73-3
Thallium (III) acetate sesquihydrate EC / List no: 219-913-2 | CAS no: 2570-63-0
Thallium (201Tl) Chloride Injection EC / List no: - | CAS no: 55172-29-7
Thallium formate EC / List no: 213-599-0 | CAS no: 992-98-3
Dithallium difluoride EC / List no: - | CAS no: 31970-97-5
Thallium selenide EC / List no: 234-895-6 | CAS no: 12039-52-0
Sulfuric acid, thallium(3+) salt (2:1), tetrahydrate EC / List no: - | CAS no: 37667-57-5
Sulfuric acid, thallium salt EC / List no: - | CAS no: 10031-59-1
Thallium hydrogen carbonate EC / List no: 249-868-4 | CAS no: 29809-42-5
Thallium triiodide EC / List no: 236-627-3 | CAS no: 13453-37-7
Thallium trichloride EC / List no: 236-625-2 | CAS no: 13453-32-2
Thallium chloride EC / List no: 232-241-4 | CAS no: 7791-12-0
Dithallium malonate EC / List no: 220-414-7 | CAS no: 2757-18-8
Thallium tribromide EC / List no: 237-232-9 | CAS no: 13701-90-1
Dithallium sulphate EC / List no: 231-201-3 | CAS no: 7446-18-6
m-Toluic acid, alpha,alpha,alpha-trifluoro-, thallium salt EC / List no: - | CAS no: 63980-13-2
Thallium(3+) perchlorate EC / List no: 239-677-4 | CAS no: 15596-83-5
Thallium arsenide EC / List no: 234-481-5 | CAS no: 12006-09-6
Slimes and Sludges, thallium
Product of adding a sulfidizer to a thallium-rich solution during lead refining. Consists primarily of thallium and cadmium sulfides.
EC / List no: 273-835-3 | CAS no: 69029-95-4
Dithallium selenide EC / List no: 239-627-1 | CAS no: 15572-25-5
Thallium triarsenide EC / List no: 281-902-3 | CAS no: 84057-85-2
Waste solids, cadmium-electrolysis, thallium-rich
Residue obtained in the electrolysis of cadmium, composed primarily of thallium chromate. Other non-ferrous metals or metal compounds may also be present.
EC / List no: 285-572-1 | CAS no: 85117-20-0
2-Butanol, 2-methyl-, thallium(1+) salt EC / List no: - | CAS no: 75222-21-8
Thallium telluride (TlTe) EC / List no: - | CAS no: 12040-12-9
Thallium iodide (TlI2) EC / List no: - | CAS no: 57232-83-4
Dithallium dichromate EC / List no: 236-626-8 | CAS no: 13453-35-5
Dithallium trioxide EC / List no: 215-229-3 | CAS no: 1314-32-5
Sulfuric acid, thallium(3+) salt (2:1), monohydrate EC / List no: - | CAS no: 37667-58-6
Dithallium sulphide EC / List no: 215-250-8 | CAS no: 1314-97-2
Sulfuric acid, aluminum thallium salt EC / List no: - | CAS no: 52238-56-9
Thallium acetate EC / List no: 239-947-1 | CAS no: 15843-14-8
Bismuth, compound with thallium (1:1) EC / List no: 234-982-9 | CAS no: 12048-36-1
Dithallium tris(sulphate) EC / List no: 240-349-8 | CAS no: 16222-66-5
Thallic nitrate, trihydrate EC / List no: 627-221-0 | CAS no: 13453-38-8
Dithallium trisulphide EC / List no: 234-886-7 | CAS no: 12039-17-7
Thallium acetate EC / List no: 209-257-5 | CAS no: 563-68-8
Residues, thallium EC / List no: - | CAS no: 69029-81-8
Thallium(i) metaborate EC / List no: - | CAS no: 16979-36-5
lambda1-thallanylium hexafluoro-lambda5-phosphanuide EC / List no: 633-081-1 | CAS no: 60969-19-9
(pentane-2,4-dionato-O,O')thallium EC / List no: 238-081-1 | CAS no: 14219-90-0
Selenious acid, dithallium(1+) salt EC / List no: - | CAS no: 15123-92-9
Thallium bromide EC / List no: 232-163-0 | CAS no: 7789-40-4
Thallium, (4-methylphenyl)bis(trifluoroacetato-O)- EC / List no: 631-044-4 | CAS no: 23586-55-2
Carbamic acid, diethyldithio-, thallium complex EC / List no: - | CAS no: 18756-72-4
Thallium(III) trifluoroacetate EC / List no: 245-761-1 | CAS no: 23586-53-0
Thallium (I) ethanolate EC / List no: 243-786-2 | CAS no: 20398-06-5
Dithallium carbonate EC / List no: 229-434-0 | CAS no: 6533-73-9
Thallium iodide EC / List no: 232-199-7 | CAS no: 7790-30-9
Cyclopentadienylthallium EC / List no: 252-229-2 | CAS no: 34822-90-7
Sulfuric acid, thallium(1+) tin(2+) salt (2:2:1) EC / List no: - | CAS no: 27790-36-9
Chloric acid, thallium(1+) salt EC / List no: - | CAS no: 13453-30-0
Thallium hydrotris(1-pyrazolyl)borate EC / List no: - | CAS no: 34269-45-9
2-fluoroacetate;thallium(1+) EC / List no: - | CAS no: 63905-90-8
Nitric acid, thallium salt EC / List no: - | CAS no: 16901-76-1
Sulfuric acid, thallium(2+) salt EC / List no: - | CAS no: 37475-01-7
Dithallium chromate EC / List no: 236-750-2 | CAS no: 13473-75-1
Thallium nitrate EC / List no: 233-273-1 | CAS no: 10102-45-1
Thallium fluoride EC / List no: 232-154-1 | CAS no: 7789-27-7
Antimony, compound with thallium (1:1) EC / List no: 249-428-1 | CAS no: 29095-38-3
Sulfuric acid, thallium(3+) salt (2:1) EC / List no: - | CAS no: 15478-75-8
Thallium trifluoride EC / List no: 232-010-8 | CAS no: 7783-57-5
Dithallium oxide EC / List no: 215-220-4 | CAS no: 1314-12-1
Thallium(3+) triformate EC / List no: 276-195-3 | CAS no: 71929-23-2
Perrhenic acid, thallium salt EC / List no: 683-357-0 | CAS no: 14013-75-3
Mercury thallium dinitrate EC / List no: 301-543-9 | CAS no: 94022-47-6
Thallium telluride (Tl2Te3) EC / List no: - | CAS no: 12040-16-3
Bismuth thallium( 1) cation pentadecaiodide EC / List no: - | CAS no: 67338-06-1
Thallium thiocyanate EC / List no: 222-571-7 | CAS no: 3535-84-0
-
-
Acute Tox. 2; STOT RE 2
uranium
231-170-6
7440-61-1
Acute Tox. 2; STOT RE 2
uranium compounds with the exception of those specified elsewhere in this Annex
show/hide
Uranium pentafluoride EC / List no: 237-405-9 | CAS no: 13775-07-0
polysilicate EC / List no: - | CAS no: 12427-14-4
Uranium diboride EC / List no: 234-508-0 | CAS no: 12007-36-2
[oxalato(2-)-O,O']dioxouranium EC / List no: 217-986-5 | CAS no: 2031-89-2
Difluorodioxouranium EC / List no: 236-898-8 | CAS no: 13536-84-0
Bis(nitrato-O,O')dioxouranium EC / List no: 253-053-9 | CAS no: 36478-76-9
Dioxobis(pentane-2,4-dionato-O,O')uranium EC / List no: 241-951-3 | CAS no: 18039-69-5
Uranium EC / List no: 231-170-6 | CAS no: 7440-61-1
Uranium tetrachloride EC / List no: 233-057-7 | CAS no: 10026-10-5
Uranium disilicide EC / List no: 234-906-4 | CAS no: 12039-85-9
Magnesium uranium(4+) hexaacetate EC / List no: 243-905-8 | CAS no: 20596-93-4
Uranium nitride EC / List no: - | CAS no: 12058-37-6
Zinc tetrakis(acetato-O)dioxouranate EC / List no: 251-762-8 | CAS no: 33959-50-1
Dichlorodioxouranium EC / List no: 232-246-1 | CAS no: 7791-26-6
Bis(formato-O)dioxouranium EC / List no: 241-063-6 | CAS no: 16984-59-1
Resin acids and Rosin acids, uranyl salts EC / List no: 273-325-0 | CAS no: 68956-97-8
Uranium tetrafluoride EC / List no: 233-170-1 | CAS no: 10049-14-6
Uranium diselenide EC / List no: 235-245-4 | CAS no: 12138-21-5
Barium uranium oxide EC / List no: - | CAS no: 10380-31-1
Uranium tetraboride EC / List no: 234-520-6 | CAS no: 12007-84-0
Acetic acid, uranium(4+) zinc salt EC / List no: 243-904-2 | CAS no: 20596-91-2
Titanate(4-), oxobis[phosphato(3-)]-, barium (1:2), uranium-doped EC / List no: 309-550-9 | CAS no: 100403-10-9
Nasturan EC / List no: 690-098-7 | CAS no: 1317-99-3
Diammonium diuranium heptaoxide EC / List no: 231-986-2 | CAS no: 7783-22-4
Nickel triuranium decaoxide EC / List no: 239-876-6 | CAS no: 15780-33-3
Uranium fluoride (U2F9) EC / List no: - | CAS no: 12134-48-4
Uranium hydride EC / List no: 257-346-2 | CAS no: 51680-55-8
Bis(nitrato-O)dioxouranium EC / List no: 233-266-3 | CAS no: 10102-06-4
Disodium heptaoxodiuranate, of uranium depleted in uranium-235 EC / List no: 237-286-3 | CAS no: 13721-34-1
Uranium carbide (UC2) EC / List no: - | CAS no: 12071-33-9
Uranium carbide (UC) EC / List no: - | CAS no: 12070-09-6
Triuranium tetraphosphide EC / List no: 234-871-5 | CAS no: 12037-84-2
Tetrakis(pentane-2,4-dionato-O,O')uranium EC / List no: 265-498-6 | CAS no: 65137-03-3
Nitric acid, uranium(6+) salt EC / List no: - | CAS no: 20820-60-4
Calcines, uranium ore-conc.
Calcined precipitates of ammonium, magnesium or sodium uranates obtained from natural uranium ores.
EC / List no: 297-819-0 | CAS no: 93763-02-1
Uranium tetrabromide EC / List no: 236-734-5 | CAS no: 13470-20-7
Sodium tris(benzeneacetato-O)dioxouranate(1-) EC / List no: 309-040-6 | CAS no: 99800-13-2
Hydrogen dioxo[phosphato(3-)-O,O']uranate(1-) EC / List no: 242-306-9 | CAS no: 18433-48-2
Uranium trioxide EC / List no: 215-701-9 | CAS no: 1344-58-7
Uranium disulphide EC / List no: 234-884-6 | CAS no: 12039-14-4
Uranium nitrate EC / List no: - | CAS no: 13826-82-9
Uranium dioxide EC / List no: 215-700-3 | CAS no: 1344-57-6
Sodium uranyl triacetate, of uranium depleted in uranium-235 EC / List no: 241-714-4 | CAS no: 17712-38-8
Bis(acetato-O)dioxouranium EC / List no: 208-767-5 | CAS no: 541-09-3
Tetraammonium uranyl tricarbonate, of uranium depleted in uranium-235 EC / List no: 241-988-5 | CAS no: 18077-77-5
Dioxo[sulphato(2-)-O]uranium EC / List no: 215-240-3 | CAS no: 1314-64-3
Disodium uranium tetraoxide EC / List no: 236-846-4 | CAS no: 13510-99-1
Bis(2-ethylhexanoato-O)dioxouranium EC / List no: 267-849-9 | CAS no: 67939-77-9
Oxobis(pentane-2,4-dionato-O,O')uranium EC / List no: 254-311-3 | CAS no: 39136-40-8
Uranium trifluoride EC / List no: 237-404-3 | CAS no: 13775-06-9
Uranate(2-), tetrakis(acetato-O)-dioxo-, magnesium (1:1), (OC-6-11)- EC / List no: - | CAS no: 66735-86-2
Uranium tetraiodide EC / List no: 236-735-0 | CAS no: 13470-22-9
Triuranium octaoxide EC / List no: 215-702-4 | CAS no: 1344-59-8
Lead uranate pigment EC / List no: 287-565-9 | CAS no: 85536-79-4
Uranium dioxideperoxide EC / List no: 234-852-1 | CAS no: 12036-71-4
Uranium triiodide EC / List no: 237-406-4 | CAS no: 13775-18-3
Nitric acid, uranium salt EC / List no: - | CAS no: 15905-86-9
Uranyl acetate-2H2O EC / List no: 629-550-5 | CAS no: 6159-44-0
Uranium hexafluoride EC / List no: 232-028-6 | CAS no: 7783-81-5
Uranium hydride (UH3) EC / List no: - | CAS no: 13598-56-6
Magnesium diuranium heptaoxide EC / List no: 236-982-4 | CAS no: 13568-61-1
Nickel uranyl tetraacetate, of uranium depleted in uranium-235 EC / List no: 275-994-4 | CAS no: 71767-12-9
Zinc bis(acetato-O)dioxouranate EC / List no: 233-390-8 | CAS no: 10138-94-0
Dipotassium heptaoxodiuranate EC / List no: 232-217-3 | CAS no: 7790-63-8
Uranium ditelluride EC / List no: 235-249-6 | CAS no: 12138-37-3
Dipotassium uranyl bis(sulphate), of uranium depleted in uranium-235 EC / List no: 262-284-4 | CAS no: 60542-74-7
Calcium diuranium heptaoxide EC / List no: 237-428-4 | CAS no: 13780-21-7
-
-
Acute Tox. 2; STOT RE 2
phosphorus trichloride
231-749-3
7719-12-2
Acute Tox. 2; STOT RE 2; Skin Corr. 1A
(RS)-4-[1-(2,3-dimethylphenyl)ethyl]-1H-imidazole; medetomidine
811-718-6
86347-14-0
Acute Tox. 2; STOT SE 3; STOT SE 1; STOT RE 1
1,5-naphthylene diisocyanate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];1,5-naphthylene diisocyanate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
221-641-4
3173-72-6
Acute Tox. 2; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2; Resp. Sens. 1; Skin Sens. 1A
boron tribromide
233-657-9
10294-33-4
Acute Tox. 2; Skin Corr. 1A
bromine
231-778-1
7726-95-6
Acute Tox. 2; Skin Corr. 1A
2-(3-(prop-1-en-2-yl)phenyl)prop-2-yl isocyanate
M-TMI
402-440-2
2094-99-7
Acute Tox. 2; Skin Corr. 1B; STOT RE 2; Resp. Sens. 1; Skin Sens. 1
formetanate (ISO); 3-[(EZ)-dimethylaminomethyleneamino]phenyl methylcarbamate
244-879-0
22259-30-9
Acute Tox. 2; Skin Sens. 1
formetanate hydrochloride; 3-(N, N-dimethylaminomethyleneamino)phenyl N-methylcarbamate
245-656-0
23422-53-9
Acute Tox. 2; Skin Sens. 1
1,1-dichloro-1-nitroethane
209-854-0
594-72-9
Acute Tox. 3
1,10-phenanthroline
200-629-2
66-71-7
Acute Tox. 3
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