EU-SAFETY_HEALTH_WORK-PREAMBLE

Safety and Health of Workers at Work Directive - Hazardous Substances

EU. Hazardous Substances for Purposes of Directive 89/391/EEC, 29 June 1989, amended by Regulation 1137/2008/EC, 21 November 2008 (Table 3/Annex VI, CLP; Annex III, 2000/54/EC)

This list contains a non-exhaustive inventory of substances that fall within the scope of the European Union's definition of hazardous chemical and biological substances, as provided on: (1) Table 3 of Annex VI to the CLP Regulation 1272/2008/EC; and (2) Annex III of Directive 2000/54/EC (Biological Agents). The EU's Occupational Safety and Health (OSH) Framework Directive 89/391/EEC applies to risks arising from chemical, physical and biological agents at the workplace.

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Last updated 23 April 2024. Database contains 4691 unique substances/entries.
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Substance Name
EC No.
CAS No.
EU CLP (1272/2008)
EU_BA Directive 2000/54/EC
endrin (ISO); 1,2,3,4,10,10-hexachloro-6,7-epoxy-1,4,4a,5,6,7,8,8a-octahydro-1,4:5,8-dimethanonaphthalene
200-775-7
72-20-8
Acute Tox. 2; Acute Tox. 3
EPTC (ISO); S-ethyl dipropylthiocarbamate
212-073-8
759-94-4
Acute Tox. 4
ethane
200-814-8
74-84-0
Flam. Gas 1; Press. Gas
ethanethiol; ethyl mercaptan
200-837-3
75-08-1
Flam. Liq. 2; Acute Tox. 4
ethyl 2-(isocyanatosulfonyl)benzoate
EPSI
410-220-2
77375-79-2
Acute Tox. 4; STOT RE 2; Eye Dam. 1; Resp. Sens. 1; Skin Sens. 1
ethyl 2-cyanoacrylate
230-391-5
7085-85-0
Eye Irrit. 2; STOT SE 3; Skin Irrit. 2
ethyl hydrogen sulfate, nickel(II) salt
275-897-7
71720-48-4
Carc. 1A; Muta. 2; Repr. 1B; STOT RE 1; Resp. Sens. 1; Skin Sens. 1
ethylamine
200-834-7
75-04-7
Flam. Gas 1; Press. Gas; Eye Irrit. 2; STOT SE 3
ethylene
200-815-3
74-85-1
Flam. Gas 1; Press. Gas; STOT SE 3
ethylene oxide; oxirane
200-849-9
75-21-8
Press. Gas; Flam. Gas 1; Carc. 1B; Muta. 1B; Repr. 1B; Acute Tox. 3; STOT SE 3; STOT RE 1; Skin Corr. 1; Eye Dam. 1
Extract residues (coal), tar oil alk., naphthalene distn. residues; Naphthalene Oil Extract Residue [The residue obtained from chemical oil extracted after the removal of naphthalene by distillation composed primarily of two to four membered condensed ring aromatic hydrocarbons and aromatic nitrogen bases.]
The residue obtained from chemical oil extracted after the removal of naphthalene by distillation composed primarily of two to four membered condensed ring aromatic hydrocarbons and aromatic nitrogen bases.
277-567-8
73665-18-6
Carc. 1B; Muta. 1B
fenoxaprop-P-ethyl (ISO); ethyl (2R)-2-{4-[(6-chloro-1,3-benzoxazol-2-yl)oxy]phenoxy}propanoate
615-273-7
71283-80-2
STOT RE 2; Skin Sens. 1
fenoxycarb (ISO); ethyl [2-(4-phenoxyphenoxy)ethyl]carbamate
276-696-7
72490-01-8
Carc. 2
fentin hydroxide (ISO); triphenyltin hydroxide
200-990-6
76-87-9
Carc. 2; Repr. 2; Acute Tox. 2; Acute Tox. 3; STOT RE 1; STOT SE 3; Skin Irrit. 2; Eye Dam. 1
fluazifop-P-butyl (ISO); butyl (R)-2-[4-(5-trifluoromethyl-2-pyridyloxy)phenoxy]propionate
616-669-2
79241-46-6
Repr. 2
fluazinam (ISO); 3-chloro-N-[3- chloro-2,6-dinitro-4-(trifluor omethyl)phenyl]-5-(trifluoromethyl)pyridin-2-amine
616-712-5
79622-59-6
Repr. 2; Acute Tox. 4; Eye Dam. 1; Skin Sens. 1A
fluorine
231-954-8
7782-41-4
Press. Gas; Ox. Gas 1; Acute Tox. 2; Skin Corr. 1A
fluorosulphonic acid
232-149-4
7789-21-1
Acute Tox. 4; Skin Corr. 1A
fomesafen (ISO); 5-[2-chloro-4-(trifluoromethyl)phenoxy]-N-(methylsulphonyl)-2-nitrobenzamide
276-439-9
72178-02-0
Acute Tox. 4
formamide
200-842-0
75-12-7
Repr. 1B
glufosinate ammonium (ISO); ammonium 2-amino-4-(hydroxymethylphosphinyl)butyrate
278-636-5
77182-82-2
Repr. 1B; Acute Tox. 4; STOT RE 2
heptachlor (ISO); 1,4,5,6,7,8,8-heptachloro-3a,4,7,7a-tetrahydro-4,7-methanoindene
200-962-3
76-44-8
Carc. 2; Acute Tox. 3; STOT RE 2
hexachlorocyclopentadiene
201-029-3
77-47-4
Acute Tox. 2; Acute Tox. 3; Acute Tox. 4; Skin Corr. 1B
hexaconazole (ISO);(RS)-2-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)hexan-2- ol
HEXACONAZOLE
413-050-7
79983-71-4
Acute Tox. 4; Skin Sens. 1
hexasodium 2,2'-vinylenebis((3- sulfonato-4,1-pheny lene)imino(6-(N-cyanoethyl-N-(2-hydroxypropyl)amino)-1,3,5-triazine-4,2-diyl)imino)dibenzene-1,4-disulfonate
BRIGHTENER SM 1018 CONC.; LEUCOPHOR BCR
405-280-1
76508-02-6
Eye Irrit. 2
hydrochloric acid ... %;hydrogen chloride
231-595-7
7647-01-0
Skin Corr. 1B; STOT SE 3
hydrochloric acid ... %;hydrogen chloride
231-595-7
7647-01-0
Press. Gas; Acute Tox. 3; Skin Corr. 1A
hydrofluoric acid ... %;hydrogen fluoride
231-634-8
7664-39-3
Acute Tox. 2; Acute Tox. 1; Skin Corr. 1A
hydrofluoric acid ... %;hydrogen fluoride
231-634-8
7664-39-3
Acute Tox. 2; Acute Tox. 1; Skin Corr. 1A
hydrogen cyanide ... %; hydrocyanic acid ... %;hydrogen cyanide; hydrocyanic acid
200-821-6
74-90-8
Flam. Liq. 1; Acute Tox. 2
hydrogen cyanide ... %; hydrocyanic acid ... %;hydrogen cyanide; hydrocyanic acid
200-821-6
74-90-8
Acute Tox. 2; Acute Tox. 1
hydrogen peroxide solution... %
231-765-0
7722-84-1
Ox. Liq. 1; Acute Tox. 4; Skin Corr. 1A
hydrogen sulphide
231-977-3
7783-06-4
Press. Gas; Acute Tox. 2
hydroxylamine ... % [> 55 % in aqueous solution];hydroxylamine ... % [≤ 55 % in aqueous solution]
232-259-2
7803-49-8
Unst. Expl.; Met. Corr. 1; Carc. 2; Acute Tox. 4; STOT RE 2; STOT SE 3; Skin Irrit. 2; Eye Dam. 1; Skin Sens. 1
hydroxylamine ... % [> 55 % in aqueous solution];hydroxylamine ... % [≤ 55 % in aqueous solution]
232-259-2
7803-49-8
Met. Corr. 1; Carc. 2; Acute Tox. 4; STOT RE 2; STOT SE 3; Skin Irrit. 2; Eye Dam. 1; Skin Sens. 1
imiprothrin (ISO); reaction mass of: [2,4-dioxo-(2-propyn-1-yl)imidazolidin-3-yl]methyl(1R)-cis-chrysanthemate; [2,4-dioxo-(2-propyn-1-yl)imidazolidin-3-yl]methyl(1R)-trans-chrysanthemate
428-790-6
72963-72-5
Carc. 2; Acute Tox. 4; STOT SE 2
iodine
231-442-4
7553-56-2
Acute Tox. 4
iron (II) sulfate
231-753-5
7720-78-7
Acute Tox. 4; Eye Irrit. 2; Skin Irrit. 2
iron (II) sulfate (1:1) heptahydrate; sulfuric acid, iron(II) salt (1:1), heptahydrate; ferrous sulfate heptahydrate
616-510-7
7782-63-0
Acute Tox. 4; Eye Irrit. 2; Skin Irrit. 2
Iron (III) tris(4-methylbenzenesulfonate)
JOF 2822 5F; JOF 2822 5FL; JOF 4443
420-960-8
77214-82-5
Eye Dam. 1
isobutane;isobutane (containing ≥ 0,1 % butadiene (203-450-8))
200-857-2
75-28-5
Flam. Gas 1; Press. Gas; Carc. 1A; Muta. 1B
isobutane;isobutane (containing ≥ 0,1 % butadiene (203-450-8))
200-857-2
75-28-5
Flam. Gas 1; Press. Gas
isobutyric acid
201-195-7
79-31-2
Acute Tox. 4
isobutyryl chloride
201-194-1
79-30-1
Flam. Liq. 2; Skin Corr. 1A
isopentane; 2-methylbutane
201-142-8
78-78-4
Flam. Liq. 1; Asp. Tox. 1; STOT SE 3
isoprene (stabilised); 2-methyl-1,3-butadiene
201-143-3
78-79-5
Flam. Liq. 1; Carc. 1B; Muta. 2
L-(+)-lactic acid; (2S)-2-hydroxypropanoic acid
201-196-2
79-33-4
Skin Corr. 1C; Eye Dam. 1
lead chromate
231-846-0
7758-97-6
Carc. 1B; Repr. 1A; STOT RE 2
lead hydrogen arsenate
232-064-2
7784-40-9
Carc. 1A; Repr. 1A; Acute Tox. 3; STOT RE 2
lead massive: [particle diameter ≥ 1 mm];lead powder [particle diameter < 1 mm]
231-100-4
7439-92-1
Repr. 1A; Lact.
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