EU-SAFETY_HEALTH_WORK-PREAMBLE

Safety and Health of Workers at Work Directive - Hazardous Substances

EU. Hazardous Substances for Purposes of Directive 89/391/EEC, 29 June 1989, amended by Regulation 1137/2008/EC, 21 November 2008 (Table 3/Annex VI, CLP; Annex III, 2000/54/EC)

This list contains a non-exhaustive inventory of substances that fall within the scope of the European Union's definition of hazardous chemical and biological substances, as provided on: (1) Table 3 of Annex VI to the CLP Regulation 1272/2008/EC; and (2) Annex III of Directive 2000/54/EC (Biological Agents). The EU's Occupational Safety and Health (OSH) Framework Directive 89/391/EEC applies to risks arising from chemical, physical and biological agents at the workplace.

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Last updated 23 April 2024. Database contains 4691 unique substances/entries.
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Substance Name
EC No.
CAS No.
EU CLP (1272/2008)
EU_BA Directive 2000/54/EC
1,2,3,4-tetrahydro-1-naphthyl hydroperoxide
212-230-0
771-29-9
Org. Perox. D; Acute Tox. 4; Skin Corr. 1B
1,2,3,4-tetrahydronaphthalene
204-340-2
119-64-2
Eye Irrit. 2; Skin Irrit. 2
1,2,3,6-tetrahydro-3,6-methanophthalic anhydride
212-557-9
826-62-0
Eye Dam. 1; Resp. Sens. 1; Skin Sens. 1
1,2,3,6-tetrahydro-3-methylphthalic anhydride
226-247-6
5333-84-6
Eye Dam. 1; Resp. Sens. 1; Skin Sens. 1
1,2,3,6-tetrahydro-4-methylphthalic anhydride
222-323-8
3425-89-6
Eye Dam. 1; Resp. Sens. 1; Skin Sens. 1
1,2,3,6-tetrahydromethylphthalic anhydride
247-830-1
26590-20-5
Eye Dam. 1; Resp. Sens. 1; Skin Sens. 1
1,2,3,6-tetrahydrophthalic anhydride
201-605-4
85-43-8
Eye Dam. 1; Resp. Sens. 1; Skin Sens. 1
1,2,3-trichloropropane
202-486-1
96-18-4
Carc. 1B; Repr. 1B; Acute Tox. 4
1,2,4-triazole
206-022-9
288-88-0
Repr. 1B; Acute Tox. 4; Eye Irrit. 2
1,2,4-trichlorobenzene
204-428-0
120-82-1
Acute Tox. 4; Skin Irrit. 2
1,2,4-trimethylbenzene
202-436-9
95-63-6
Flam. Liq. 3; Acute Tox. 4; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2
1,2,5,6,9,10-hexabromocyclododecane
221-695-9
3194-55-6
Repr. 2; Lact.
1,2-benzenedicarboxylic acid, dihexyl ester, branched and linear
271-093-5
68515-50-4
Repr. 1B
1,2-benzenedicarboxylic acid, dipentylester, branched and linear
284-032-2
84777-06-0
Repr. 1B
1,2-benzenedicarboxylic acid; di-C6-8-branched alkylesters, C7-rich
276-158-1
71888-89-6
Repr. 1B
1,2-benzenedicarboxylic acid; di-C7-11-branched and linear alkylesters
271-084-6
68515-42-4
Repr. 1B
1,2-benzisothiazol-3(2H)-one; 1,2-benzisothiazolin-3-one
220-120-9
2634-33-5
Acute Tox. 2; Acute Tox. 4; Skin Irrit. 2; Eye Dam. 1; Skin Sens. 1A
1,2-bis(2-methoxyethoxy)ethane; TEGDME; triethylene glycol dimethyl ether; triglyme
203-977-3
112-49-2
Repr. 1B
1,2-dibromo-3-chloropropane
202-479-3
96-12-8
Carc. 1B; Muta. 1B; Repr. 1A; Acute Tox. 3; STOT RE 2
1,2-dibromoethane
203-444-5
106-93-4
Carc. 1B; Acute Tox. 3; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2
1,2-dichlorobenzene; o-dichlorobenzene
202-425-9
95-50-1
Acute Tox. 4; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2
1,2-dichloroethane; ethylene dichloride
203-458-1
107-06-2
Flam. Liq. 2; Carc. 1B; Acute Tox. 4; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2
1,2-dichloroethylene
208-750-2
540-59-0
Flam. Liq. 2; Acute Tox. 4
1,2-dichloropropane; propylene dichloride
201-152-2
78-87-5
Flam. Liq. 2; Carc. 1B; Acute Tox. 4
1,2-diethoxyethane
211-076-1
629-14-1
Flam. Liq. 2; Repr. 1A; Eye Irrit. 2
1,2-dihydroxybenzene; pyrocatechol
204-427-5
120-80-9
Carc. 1B; Muta. 2; Acute Tox. 3; Eye Irrit. 2; Skin Irrit. 2
1,2-dimethoxyethane; ethylene glycol dimethyl ether; EGDME
203-794-9
110-71-4
Flam. Liq. 2; Repr. 1B; Acute Tox. 4
1,2-dimethyl-3,5-diphenylpyra zolium methylsulphate; difenzoquat methyl sulfate
256-152-5
43222-48-6
Acute Tox. 4
1,2-dimethylimidazole
217-101-2
1739-84-0
Acute Tox. 4; Skin Irrit. 2; Eye Dam. 1
1,2-dinitrobenzene
208-431-8
528-29-0
Acute Tox. 2; Acute Tox. 1; STOT RE 2
1,2-epoxybutane
203-438-2
106-88-7
Flam. Liq. 2; Carc. 2; Acute Tox. 4; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2
1,3,5-triazine-2,4,6-triamine; melamine
203-615-4
108-78-1
Carc. 2; STOT RE 2
1,3,5-trinitrobenzene
202-752-7
99-35-4
Expl. 1.1; Acute Tox. 2; Acute Tox. 1; STOT RE 2
1,3,5-trioxan; trioxymethylene
203-812-5
110-88-3
Flam. Sol. 1; Repr. 2; STOT SE 3
1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione; TGIC
219-514-3
2451-62-9
Muta. 1B; Acute Tox. 3; STOT RE 2; Eye Dam. 1; Skin Sens. 1
1,3-bis(1-isocyanato-1-methylethyl)benzene; [m-TMXDI]
220-474-4
2778-42-9
Resp. Sens. 1; Skin Sens. 1A
1,3-bis(2,3-epoxypropoxy)-2,2-dimethylpropane
241-536-7
17557-23-2
Skin Irrit. 2; Skin Sens. 1
1,3-bis(isocyanatomethyl)benzene; [m-XDI]
222-852-4
3634-83-1
Resp. Sens. 1; Skin Sens. 1A
1,3-butadiene; buta-1,3-diene
203-450-8
106-99-0
Flam. Gas 1; Press. Gas; Carc. 1A; Muta. 1B
1,3-dichlorbenzene
208-792-1
541-73-1
Acute Tox. 4
1,3-dichloro-2-propanol
202-491-9
96-23-1
Carc. 1B; Acute Tox. 3; Acute Tox. 4
1,3-dichloropropene
208-826-5
542-75-6
Flam. Liq. 3; Acute Tox. 3; Acute Tox. 4; Asp. Tox. 1; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2; Skin Sens. 1
1,3-dinitrobenzene
202-776-8
99-65-0
Acute Tox. 2; Acute Tox. 1; STOT RE 2
1,3-dioxolane
211-463-5
646-06-0
Flam. Liq. 2
1,3-diphenylguanidine
203-002-1
102-06-7
Repr. 2; Acute Tox. 4; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2
1,3-propanesultone; 1,2-oxathiolane 2,2-dioxide
214-317-9
1120-71-4
Carc. 1B; Acute Tox. 4
1,3-propylene oxide
207-964-3
503-30-0
Flam. Liq. 2; Acute Tox. 4
1,4,5,6,7,7-hexachlorobicyclo [2,2,1]hept-5-ene-2,3-dicarboxylicanhydride chlorendic anhydride
204-077-3
115-27-5
Eye Irrit. 2; STOT SE 3; Skin Irrit. 2
1,4,5,8-tetraaminoanthra; quinone; C.I. Disperse Blue 1
219-603-7
2475-45-8
Carc. 1B; Skin Irrit. 2; Eye Dam. 1; Skin Sens. 1
1,4-Benzenediamine, N,N’-mixed Ph and tolyl derivs.
273-227-8
68953-84-4
Repr. 1B; Skin Sens. 1
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