Authorisation List

List of substances included in Annex XIV of REACH ("Authorisation List").

Companies that want to continue using a substance included in the Authorisation List after the sunset date need to prepare an application for authorisation, submit it before the latest application date and have a positive authorisation decision by the European Commission. The latest application date and the sunset date are specified in the Authorisation List.

Please be reminded that this list is provided for information purposes only. Only the text of Annex XIV as published in the Official Journal of the EU is authentic and produces legal effects.

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Substance Identifier

Entry number in Annex XIV:

Date of inclusion in Authorisation List:

Latest application date:

Sunset Date:

Intrinsic property(ies) referred to in Article 57:

Substance name	EC No.	CAS No.	Entry No.	Latest application date	Sunset Date	Intrinsic property
1,2-benzenedicarboxylic acid, di-C6-10-alkyl esters or mixed decyl and hexyl and octyl diesters with ≥ 0.3% of dihexyl phthalate (EC No. 201-559-5) show/hide 1,2-Benzenedicarboxylic acid, mixed decyl and hexyl and octyl diesters EC No.: 272-013-1 \| CAS No.: 68648-93-1 1,2-Benzenedicarboxylic acid, di-C6-10-alkyl esters EC No.: 271-094-0 \| CAS No.: 68515-51-5	-	-	46	27-Aug-2021	27-Feb-2023	Toxic for reproduction (Article 57c)	Details
4-(1,1,3,3-tetramethylbutyl)phenol, ethoxylated covering well-defined substances and UVCB substances, polymers and homologues show/hide 20-[4-(1,1,3,3-tetramethylbutyl)phenoxy]-3,6,9,12,15,18-hexaoxaicosan-1-ol EC No.: 219-682-8 \| CAS No.: 2497-59-8 Poly(oxy-1,2-ethanediyl), α-[(1,1,3,3-tetramethylbutyl)phenyl]-ω-hydroxy- EC No.: 618-541-1 \| CAS No.: 9036-19-5 2-[4-(1,1,3,3-tetramethylbutyl)phenoxy]ethanol EC No.: 621-345-9 \| CAS No.: 2315-67-5 2-{2-[4-(2,4,4-trimethylpentan-2-yl)phenoxy]ethoxy}ethanol EC No.: 621-341-7 \| CAS No.: 2315-61-9 Polyethylene glycol p-(1,1,3,3-tetramethylbutyl)phenyl ether EC No.: 618-344-0 \| CAS No.: 9002-93-1	-	-	42	04-Jul-2019	04-Jan-2021	Endocrine disrupting properties (Article 57(f) - environment)	Details
4-Nonylphenol, branched and linear, ethoxylated substances with a linear and/or branched alkyl chain with a carbon number of 9 covalently bound in position 4 to phenol, ethoxylated covering UVCB- and well-defined substances, polymers and homologues, which include any of the individual isomers and/or combinations thereof show/hide 4-Nonylphenol, ethoxylated 1 - 2.5 moles ethoxylated EC No.: 500-045-0 \| CAS No.: 26027-38-3 Nonylphenol, ethoxylated EC No.: 500-024-6 \| CAS No.: 9016-45-9 2-[2-[2-[2-(4-nonylphenoxy)ethoxy]ethoxy]ethoxy]ethanol EC No.: 230-770-5 \| CAS No.: 7311-27-5 2-[2-(4-nonylphenoxy)ethoxy]ethanol EC No.: 243-816-4 \| CAS No.: 20427-84-3 Nonylphenol, ethoxylated (15-EO) EC No.: 931-756-8 \| CAS No.: - Nonylphenol, ethoxylated (10-EO) EC No.: 931-755-2 \| CAS No.: - Nonylphenol, branched, ethoxylated 1 - 2.5 moles ethoxylated EC No.: 500-209-1 \| CAS No.: 68412-54-4 20-(4-nonylphenoxy)-3,6,9,12,15,18-hexaoxaicosan-1-ol EC No.: 248-743-1 \| CAS No.: 27942-27-4 Nonylphenol, ethoxylated (6,5-EO) EC No.: 931-753-1 \| CAS No.: - Poly(oxy-1,2-ethanediyl), α-(nonylphenyl)-ω-hydroxy-, branched EC No.: 932-688-1 \| CAS No.: - 26-(4-Nonylphenoxy)-3,6,9,12,15,18,21,24- octaoxahexacosan -1-ol EC No.: 604-395-6 \| CAS No.: 14409-72-4 Poly (oxy-1,2-ethanediyl), alpha -(nonylphenyl)-omega-hydroxy-, branched EC No.: 932-337-2 \| CAS No.: - Nonylphenol, ethoxylated (8-EO) EC No.: 931-754-7 \| CAS No.: - 2-{2-[4-(3,6-dimethylheptan-3-yl)phenoxy]ethoxy}ethanol EC No.: 687-833-9 \| CAS No.: 1119449-38-5 Nonylphenol, ethoxylated (polymer) EC No.: 938-618-6 \| CAS No.: - Nonylphenol, ethoxylated (EO = 4) EC No.: - \| CAS No.: - Nonylphenol, ethoxylated (10-EO) (9016-45-9) EC No.: 939-993-9 \| CAS No.: - 4-Nonylphenol, branched, ethoxylated 1 - 2.5 moles ethoxylated EC No.: 500-315-8 \| CAS No.: 127087-87-0 17-(4-nonylphenoxy)-3,6,9,12,15-pentaoxaheptadecan-1-ol EC No.: - \| CAS No.: 34166-38-6 Isononylphenol, ethoxylated EC No.: 609-346-2 \| CAS No.: 37205-87-1 2-(4-nonylphenoxy)ethanol EC No.: - \| CAS No.: 104-35-8 4-t-Nonylphenol-diethoxylate EC No.: - \| CAS No.: 156609-10-8 3,6,9,12-Tetraoxatetradecan-1-ol, 14-(4-nonylphenoxy)- EC No.: - \| CAS No.: 20636-48-0 3,6,9,12,15-Pentaoxaheptadecan-1-ol, 17-(nonylphenoxy)- EC No.: - \| CAS No.: 27177-01-1 3,6,9,12,15,18,21,24,27-Nonaoxanonacosan-1-ol, 29-(isononylphenoxy)- EC No.: - \| CAS No.: 65455-72-3 44-(nonylphenoxy)-3,6,9,12,15,18,21,24,27,30,33,36,39,42-tetradecaoxatetratetracontanol EC No.: 260-678-0 \| CAS No.: 57321-10-5 20-(isononylphenoxy)-3,6,9,12,15,18-hexaoxaicosan-1-ol EC No.: 265-785-6 \| CAS No.: 65455-69-8 3,6,9,12-Tetraoxatetradecan-1-ol, 14-(4-nonylphenoxy)-, branched EC No.: 293-926-1 \| CAS No.: 91648-64-5 Nonylphenolpolyglycolether EC No.: 932-998-7 \| CAS No.: - 4-Nonylphenol, branched, ethoxylated (CAS: 127087-87-0) EC No.: 932-098-4 \| CAS No.: - 2-(isononylphenoxy)ethanol EC No.: 284-987-5 \| CAS No.: 85005-55-6 26-(nonylphenoxy)-3,6,9,12,15,18,21,24-octaoxahexacosan-1-ol EC No.: 255-695-5 \| CAS No.: 42173-90-0 2-(nonylphenoxy)ethanol EC No.: 248-762-5 \| CAS No.: 27986-36-3 29-(nonylphenoxy)-3,6,9,12,15,18,21,24,27-nonaoxanonacosanol EC No.: 248-294-1 \| CAS No.: 27177-08-8 23-(nonylphenoxy)-3,6,9,12,15,18,21-heptaoxatricosan-1-ol EC No.: 248-293-6 \| CAS No.: 27177-05-5 20-(nonylphenoxy)-3,6,9,12,15,18-hexaoxaicosan-1-ol EC No.: 248-292-0 \| CAS No.: 27177-03-3 2-[2-(nonylphenoxy)ethoxy]ethanol EC No.: 248-291-5 \| CAS No.: 27176-93-8 26-(nonylphenoxy)-3,6,9,12,15,18,21,24-octaoxahexacosan-1-ol EC No.: 247-816-5 \| CAS No.: 26571-11-9 14-(nonylphenoxy)-3,6,9,12-tetraoxatetradecan-1-ol EC No.: 247-555-7 \| CAS No.: 26264-02-8 Poly(oxy-1,2-ethanediyl), a-(nonylphenyl)-w-hydroxy- (CAS 9016-45-9) EC No.: 931-562-3 \| CAS No.: - 2-[4-(3,6-dimethylheptan-3-yl)phenoxy]ethanol EC No.: 687-832-3 \| CAS No.: 1119449-37-4	-	-	43	04-Jul-2019	04-Jan-2021	Endocrine disrupting properties (Article 57(f) - environment)	Details
5-sec-butyl-2-(2,4-dimethylcyclohex-3-en-1-yl)-5-methyl-1,3-dioxane [1], 5-sec-butyl-2-(4,6-dimethylcyclohex-3-en-1-yl)-5-methyl-1,3-dioxane [2] covering any of the individual stereoisomers of [1] and [2] or any combination thereof show/hide Reaction mass of 5-[(2R)-butan-2-yl]-2-[(1R,2R)-2,4-dimethylcyclohex-3-en-1-yl]-5-methyl-1,3-dioxane and 5-[(2R)-butan-2-yl]-2-[(1R,6R)-4,6-dimethylcyclohex-3-en-1-yl]-5-methyl-1,3-dioxane and 5-[(2S)-butan-2-yl]-2-[(1R,2R)-2,4-dimethylcyclohex-3-en-1-yl]-5-methyl-1,3-dioxane and 5-[(2S)-butan-2-yl]-2-[(1S,2R)-2,4-dimethylcyclohex-3-en-1-yl]-5-methyl-1,3-dioxane and 5-[(2S)-butan-2-yl]-2-[(1S,6R)-4,6-dimethylcyclohex-3-en-1-yl]-5-methyl-1,3-dioxane EC No.: 700-927-7 \| CAS No.: - 1,3-Dioxane, 2-[(1S,2S)-2,4-dimethyl-3-cyclohexen-1-yl]-5-methyl-5-(1-methylpropyl)-, trans- EC No.: - \| CAS No.: 676367-06-9 5-sec-butyl-2-(4,6-dimethylcyclohex-3-en-1-yl)-5-methyl-1,3-dioxane EC No.: - \| CAS No.: - Reaction mass of 5-sec-butyl-2-(2,4-dimethylcyclohex-3-en-1-yl)-5-methyl-1,3-dioxane and 5-sec-butyl-2-(4,6-dimethylcyclohex-3-en-1-yl)-5-methyl-1,3-dioxane EC No.: 413-720-9 \| CAS No.: - 1,3-Dioxane, 2-(2,4-dimethyl-3-cyclohexen-1-yl)-5-methyl-5-(1-methylpropyl)- EC No.: 601-499-3 \| CAS No.: 117933-89-8 1,3-Dioxane, 2-(2,4-dimethyl-3-cyclohexen-1-yl)-5-methyl-5-(1-methylpropyl)- EC No.: - \| CAS No.: 186309-28-4 1,3-Dioxane, 2-[(1R,2R)-2,4-dimethyl-3-cyclohexen-1-yl]-5-methyl-5-(1-methylpropyl)-, cis- EC No.: - \| CAS No.: 676367-05-8 1,3-Dioxane, 2-[(1R,2R)-2,4-dimethyl-3-cyclohexen-1-yl]-5-methyl-5-(1-methylpropyl)-, cis-rel- EC No.: - \| CAS No.: 343934-04-3 1,3-Dioxane, 2-[(1R,2R)-2,4-dimethyl-3-cyclohexen-1-yl]-5-methyl-5-(1-methylpropyl)-, trans- EC No.: - \| CAS No.: 676367-09-2 1,3-Dioxane, 2-[(1R,2R)-2,4-dimethyl-3-cyclohexen-1-yl]-5-methyl-5-(1-methylpropyl)-, trans-rel- EC No.: - \| CAS No.: 343934-05-4 1,3-Dioxane, 2-[(1R,2S)-2,4-dimethyl-3-cyclohexen-1-yl]-5-methyl-5-(1-methylpropyl)-, cis- EC No.: - \| CAS No.: 676367-04-7 1,3-Dioxane, 2-[(1R,2S)-2,4-dimethyl-3-cyclohexen-1-yl]-5-methyl-5-(1-methylpropyl)-, trans- EC No.: - \| CAS No.: 676367-08-1 1,3-Dioxane, 2-[(1S,2R)-2,4-dimethyl-3-cyclohexen-1-yl]-5-methyl-5-(1-methylpropyl)-, cis- EC No.: - \| CAS No.: 676367-03-6 1,3-Dioxane, 2-[(1S,2R)-2,4-dimethyl-3-cyclohexen-1-yl]-5-methyl-5-(1-methylpropyl)-, trans- EC No.: - \| CAS No.: 676367-07-0 1,3-Dioxane, 2-[(1S,2S)-2,4-dimethyl-3-cyclohexen-1-yl]-5-methyl-5-(1-methylpropyl)-, cis- EC No.: - \| CAS No.: 676367-02-5 5-sec-butyl-2-(2,4-dimethylcyclohex-3-en-1-yl)-5-methyl-1,3-dioxane EC No.: - \| CAS No.: -	-	-	50	27-Feb-2022	27-Aug-2023	vPvB (Article 57e)	Details
Acids generated from chromium trioxide and their oligomers show/hide Chromic acid EC No.: 231-801-5 \| CAS No.: 7738-94-5 Oligomers of chromic acid and dichromic acid EC No.: - \| CAS No.: - Dichromic acid EC No.: 236-881-5 \| CAS No.: 13530-68-2	-	-	17	21-Mar-2016	21-Sep-2017	Carcinogenic (Article 57a)	Details
Hexabromocyclododecane (HBCDD) and all major diastereoisomers identified show/hide 1,2,5,6,9,10-hexabromocyclododecane EC No.: 221-695-9 \| CAS No.: 3194-55-6 gamma-hexabromocyclododecane EC No.: - \| CAS No.: 134237-52-8 Hexabromocyclododecane EC No.: 247-148-4 \| CAS No.: 25637-99-4 alpha-hexabromocyclododecane EC No.: - \| CAS No.: 134237-50-6 beta-hexabromocyclododecane EC No.: - \| CAS No.: 134237-51-7	-	-	03	21-Feb-2014	21-Aug-2015	PBT (Article 57d)	Details
Reaction products of 1,3,4-thiadiazolidine-2,5-dithione, formaldehyde and 4-heptylphenol, branched and linear (RP-HP) with ≥0.1% w/w 4-heptylphenol, branched and linear (4-HPbl) show/hide Reaction product of 1,3,4-thiadiazolidine-2,5-dithione, formaldehyde and phenol, heptyl derivs. EC No.: 939-460-0 \| CAS No.: 1471311-26-8 Formaldehyde, reaction products with branched and linear heptylphenol, carbon disulfide and hydrazine EC No.: 300-298-5 \| CAS No.: 93925-00-9	-	-	57	01-Nov-2023	01-May-2025	Endocrine disrupting properties (Article 57(f) - environment)	Details
Sodium perborate, perboric acid, sodium salt show/hide Perboric acid, sodium salt, tetrahydrate () EC No.: - \| CAS No.: - Perboric acid (HBO(O2)), sodium salt, tetrahydrate EC No.: 600-611-8 \| CAS No.: 10486-00-7 Sodium perborate monohydrate EC No.: 600-419-4 \| CAS No.: 10332-33-9 Sodium perborate EC No.: 239-172-9 \| CAS No.: 15120-21-5 Borate(2-), tetrahydroxybis[μ-(peroxy-κO1:κO2)]di-, sodium (1:2) EC No.: - \| CAS No.: 90568-23-3 Borate(2-), tetrahydroxybis[μ-(peroxy-κO1:κO2)]di-, sodium, hydrate (1:2:6) EC No.: - \| CAS No.: 125022-34-6 Perboric acid, sodium salt EC No.: 234-390-0 \| CAS No.: 11138-47-9 Perboric acid (H3BO2(O2)), monosodium salt, trihydrate EC No.: 603-902-8 \| CAS No.: 13517-20-9	-	-	48	27-Nov-2021	27-May-2023	Toxic for reproduction (Article 57c)	Details
Tetraethyllead	201-075-4	78-00-2	55	01-Nov-2023	01-May-2025	Toxic for reproduction (Article 57c)	Details
Trichloroethylene	201-167-4	79-01-6	15	21-Oct-2014	21-Apr-2016	Carcinogenic (Article 57a)	Details

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